Studies of the Local Structure and the g Factors of the Cu(2+) Site in Y(2)BaCuO(5)
文献类型:期刊论文
作者 | H. M. Zhang ; S. Y. Wu ; Y. X. Hu ; X. F. Wang |
刊名 | Journal of Superconductivity and Novel Magnetism
![]() |
出版日期 | 2010 |
卷号 | 23期号:5页码:833-835 |
关键词 | Crystal fields and spin Hamiltonians Electron paramagnetic resonance Cu(2+) Y(2)BaCuO(5) crystal |
ISSN号 | 1557-1939 |
中文摘要 | The local structure and the g factors (g(x), g(y), and g(z)) of the Cu(2+) site in Y(2)BaCuO(5) are theoretically studied using the perturbation formulas of the g factors for a 3d(9) ion in orthorhombically elongated octahedra. The orthorhombic field parameters in these formulas are determined from the superposition model and the local geometry of the system. From the calculations, the oxygen octahedron is found to undergo the local elongation Delta Z (approximate to 0.05 angstrom) along c-axis and the relative bond length variation Delta X (approximate to 0.1 angstrom) along a- and b-axes, respectively. The calculated g factors based on the above local structure are in good agreement with the experimental data. The relationships between the anisotropies of the g factors and the low symmetrical (orthorhombic) distortions of the Cu(2+) site in Y(2)BaCuO(5) are discussed. |
原文出处 | |
公开日期 | 2012-04-13 |
源URL | [http://210.72.142.130/handle/321006/31693] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | H. M. Zhang,S. Y. Wu,Y. X. Hu,et al. Studies of the Local Structure and the g Factors of the Cu(2+) Site in Y(2)BaCuO(5)[J]. Journal of Superconductivity and Novel Magnetism,2010,23(5):833-835. |
APA | H. M. Zhang,S. Y. Wu,Y. X. Hu,&X. F. Wang.(2010).Studies of the Local Structure and the g Factors of the Cu(2+) Site in Y(2)BaCuO(5).Journal of Superconductivity and Novel Magnetism,23(5),833-835. |
MLA | H. M. Zhang,et al."Studies of the Local Structure and the g Factors of the Cu(2+) Site in Y(2)BaCuO(5)".Journal of Superconductivity and Novel Magnetism 23.5(2010):833-835. |
入库方式: OAI收割
来源:金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。