Effects of Concentration, Temperature and Hydrostatic Pressure on the Local Lattice Structure of Ni(2+) Doped Zn(BF(4))(2) center dot 6H(2)O Crystal
文献类型：期刊论文
| 作者 | M. L. Gao ; X. Y. Kuang ; H. F. Li ; H. Q. Wang |
| 刊名 | Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences
 |
| 出版日期 | 2009 |
| 卷号 | 64期号:7-8页码:511-517 |
| ISSN号 | 0932-0784 |
| 关键词 | Local Structure Zn(BF(4))(2) center dot 6H(2)O:Ni(2+) System Complete Energy Matrices optical-absorption epr-spectra mn2+ ions nickel endor |
| 中文摘要 | A theoretical method for studying the inter-relationship between electronic and molecular structure is presented by means of complete energy matrices. As an application, the effects of temperature, concentration and hydrostatic pressure on the local structures of Ni(2+) doped Zn(BF(4))(2) center dot 6H(2)O crystal have been Studied. Our results show that the local lattice structures of [Ni(H(2)O)(6)](2+) coordination complex have expansion distortions as the temperature rises. Meanwhile, we find that the local structure parameter theta becomes smaller with the increasing concentration of Ni(2+) ions doped in Zn(BF(4))(2) center dot 6H(2)O crystal. Furthermore, the pressure dependence of theta and anisotropic g-factors are discussed and the relationship between zero-field splitting parameter D and Delta g is determined. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/31924]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | M. L. Gao,X. Y. Kuang,H. F. Li,et al. Effects of Concentration, Temperature and Hydrostatic Pressure on the Local Lattice Structure of Ni(2+) Doped Zn(BF(4))(2) center dot 6H(2)O Crystal[J]. Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,2009,64(7-8):511-517. |
| APA | M. L. Gao,X. Y. Kuang,H. F. Li,&H. Q. Wang.(2009).Effects of Concentration, Temperature and Hydrostatic Pressure on the Local Lattice Structure of Ni(2+) Doped Zn(BF(4))(2) center dot 6H(2)O Crystal.Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,64(7-8),511-517. |
| MLA | M. L. Gao,et al."Effects of Concentration, Temperature and Hydrostatic Pressure on the Local Lattice Structure of Ni(2+) Doped Zn(BF(4))(2) center dot 6H(2)O Crystal".Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences 64.7-8(2009):511-517. |
入库方式： OAI收割
来源：金属研究所
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