Enhanced Photoelectrochemical Performance of WO(3) Film Electrode under Visible Light by Electrochemical Etching Fluorination in Aqueous Solutions Containing Fluorine
文献类型：期刊论文
| 作者 | W. Li ; W. H. Leng ; Z. J. Niu ; X. Li ; H. Fei ; J. Q. Zhang ; C. N. Cao |
| 刊名 | Acta Physico-Chimica Sinica
 |
| 出版日期 | 2009 |
| 卷号 | 25期号:12页码:2427-2432 |
| 关键词 | WO(3) Electrochemical etching Fluorination Photoelectrochemistry Visible light tungsten-oxide degradation oxidation tio2 photocatalysts |
| ISSN号 | 1000-6818 |
| 中文摘要 | A new and simple method of electrochemical etching in acidic aqueous solutions containing fluorine for the electrodeposited WO(3) thin films is presented. The samples were characterized by photoelectrochemistry, scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV-Vis diffuse reflectance spectroscopy, and photoluminescence (PL). Results showed that the etching increased the specific surface area with a concomitant reduction in the catalyst mass and also a change in the surface status of the electrodes. This modification of the surface status improved the photoelectrochemical performance of the electrodes under visible and UV-Vis light illumination with the same mass and specific surface area. This enhancement can be ascribed to the surface fluorination of the electrodes, which result in a decrease in the surface recombination centers and a negative shift in the flatband potential. The light absorption and crystalline were found to be unchanged by etching. The etched WO(3) film electrode shows excellent photoelectrochemical stability in acid solutions. This provides a novel method for increasing the photon electric conversion efficiency of WO(3) thin film electrodes. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/32036]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | W. Li,W. H. Leng,Z. J. Niu,et al. Enhanced Photoelectrochemical Performance of WO(3) Film Electrode under Visible Light by Electrochemical Etching Fluorination in Aqueous Solutions Containing Fluorine[J]. Acta Physico-Chimica Sinica,2009,25(12):2427-2432. |
| APA | W. Li.,W. H. Leng.,Z. J. Niu.,X. Li.,H. Fei.,...&C. N. Cao.(2009).Enhanced Photoelectrochemical Performance of WO(3) Film Electrode under Visible Light by Electrochemical Etching Fluorination in Aqueous Solutions Containing Fluorine.Acta Physico-Chimica Sinica,25(12),2427-2432. |
| MLA | W. Li,et al."Enhanced Photoelectrochemical Performance of WO(3) Film Electrode under Visible Light by Electrochemical Etching Fluorination in Aqueous Solutions Containing Fluorine".Acta Physico-Chimica Sinica 25.12(2009):2427-2432. |
入库方式： OAI收割
来源：金属研究所
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