Study on impedance spectra of La(0.7)Sr(0.3)MnO(3) and Sm(0.2)Ce(0.8)O(1.9)-impregnated La(0.7)Sr(0.3)MnO(3) cathode in single chamber fuel cell condition
文献类型:期刊论文
作者 | M. L. Liu ; Z. Lue ; B. Wei ; X. Q. Huang ; K. F. Chen ; W. H. Su |
刊名 | Electrochimica Acta
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出版日期 | 2009 |
卷号 | 54期号:20页码:4726-4730 |
关键词 | Impedance spectroscopy Strontium-doped LaMnO(3) cathode Single chamber fuel cell condition CH(4)/O(2) ratio Methane-oxygen mixtures performance anode sofc spectroscopy electrode |
ISSN号 | 0013-4686 |
中文摘要 | Impedance spectroscopy was used to study the electrochemical performance of pure and ion-impregnated La(0.7)Sr(0.3)MnO(3) (LSM) cathodes on YSZ (Y(2)O(3)-stabilized ZrO(2)) electrolytes in single chamber fuel cell conditions, i.e. a mixture gas with oxygen as oxidant, methane as fuel and nitrogen as dilute gas. Measurements were taken at the furnace temperature range of 550-750 degrees C and the CH(4)/O(2) ratios from 1 to 2. Polarization resistances (R(p)) for pure and impregnated LSM cathodes increased obviously as the CH(4)/O(2) ratio increased at 650-750 degrees C. Polarization resistances of Sm(0.2)Ce(0.8)O(1.9) (SDC) impregnated LSM cathode were much smaller than the ones of pure LSM cathode under the same conditions. Overtemperatures were occurred at both cathodes due to the partial oxidation of methane. (C) 2009 Elsevier Ltd. All rights reserved. |
原文出处 | |
公开日期 | 2012-04-13 |
源URL | [http://210.72.142.130/handle/321006/32103] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | M. L. Liu,Z. Lue,B. Wei,et al. Study on impedance spectra of La(0.7)Sr(0.3)MnO(3) and Sm(0.2)Ce(0.8)O(1.9)-impregnated La(0.7)Sr(0.3)MnO(3) cathode in single chamber fuel cell condition[J]. Electrochimica Acta,2009,54(20):4726-4730. |
APA | M. L. Liu,Z. Lue,B. Wei,X. Q. Huang,K. F. Chen,&W. H. Su.(2009).Study on impedance spectra of La(0.7)Sr(0.3)MnO(3) and Sm(0.2)Ce(0.8)O(1.9)-impregnated La(0.7)Sr(0.3)MnO(3) cathode in single chamber fuel cell condition.Electrochimica Acta,54(20),4726-4730. |
MLA | M. L. Liu,et al."Study on impedance spectra of La(0.7)Sr(0.3)MnO(3) and Sm(0.2)Ce(0.8)O(1.9)-impregnated La(0.7)Sr(0.3)MnO(3) cathode in single chamber fuel cell condition".Electrochimica Acta 54.20(2009):4726-4730. |
入库方式: OAI收割
来源:金属研究所
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