EPR investigation of local structure for Mn(H(2)O)(6) (2+) cluster in M(H(2)O)(6) XCl(6): Mn(2+) (M = Zn, Mg, Cd, Ca; X = Pt, Sn) systems at different temperatures
文献类型：期刊论文
| 作者 | W. Y. Tian ; X. Y. Kuang ; H. F. Li ; Y. F. Li ; Li Ying |
| 刊名 | Chemical Physics Letters
 |
| 出版日期 | 2009 |
| 卷号 | 468期号:4-6页码:325-329 |
| 关键词 | electron-paramagnetic-resonance single-crystals spectra field ions spectroscopy copper(ii) complexes behavior mn(ii) |
| ISSN号 | 0009-2614 |
| 中文摘要 | A theoretical method for studying the inter-relation between the local structure and EPR spectra is established by diagonalizing the complete energy matrices. For [M(H(2)O)(6)]XCl(6): Mn(2+) (M = Zn, Mg, Cd, Ca; X = Pt, Sn) systems, the calculated results demonstrate that the local structures around the octahedral Mn(2+) centers in the doped systems are very similar despite of the host crystals being different. Furthermore, it is shown that the EPR zero-field parameter D depends simultaneously on the local structure parameters R and h while (a - F) depends mainly on R, whether the doped systems are at liquid-nitrogen temperature or room temperature. (C) 2008 Elsevier B.V. All rights reserved. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/32331]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | W. Y. Tian,X. Y. Kuang,H. F. Li,et al. EPR investigation of local structure for Mn(H(2)O)(6) (2+) cluster in M(H(2)O)(6) XCl(6): Mn(2+) (M = Zn, Mg, Cd, Ca; X = Pt, Sn) systems at different temperatures[J]. Chemical Physics Letters,2009,468(4-6):325-329. |
| APA | W. Y. Tian,X. Y. Kuang,H. F. Li,Y. F. Li,&Li Ying.(2009).EPR investigation of local structure for Mn(H(2)O)(6) (2+) cluster in M(H(2)O)(6) XCl(6): Mn(2+) (M = Zn, Mg, Cd, Ca; X = Pt, Sn) systems at different temperatures.Chemical Physics Letters,468(4-6),325-329. |
| MLA | W. Y. Tian,et al."EPR investigation of local structure for Mn(H(2)O)(6) (2+) cluster in M(H(2)O)(6) XCl(6): Mn(2+) (M = Zn, Mg, Cd, Ca; X = Pt, Sn) systems at different temperatures".Chemical Physics Letters 468.4-6(2009):325-329. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。