In situ characterization of localized corrosion of stainless steel by scanning electrochemical microscope
文献类型:期刊论文
作者 | Y. H. Yin ; L. Niu ; M. Lu ; W. K. Guo ; S. H. Chen |
刊名 | Applied Surface Science
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出版日期 | 2009 |
卷号 | 255期号:22页码:9193-9199 |
关键词 | Localized corrosion 304 stainless steel Characterization In situ Scanning electrochemical microscope (SECM) phase ion gun pitting corrosion impedance spectroscopy galvanic corrosion current-density passive film kelvin probe iron secm breakdown |
ISSN号 | 0169-4332 |
中文摘要 | Scanning electrochemical microscopy (SECM) area scan measurements have been performed to investigate the localized corrosion of type 304 stainless steel in neutral chloride solution. Variations in the Faradaic current measured at selected tip potential values can be related to changes in the local concentration and electrochemical activities of electroactive species involved in corrosion reactions occurring at the substrate as a function of immersion times of the substrate and polarized currents or potentials applied on the substrate. To further verify the results acquired from cyclic voltammetric experiments, SECM measurements were employed to in situ study the compositions and electrochemical activity distribution pro. le of the pitting corrosion products of stainless steel. It has been demonstrated that the combination of feedback current mode with generation-collection (G-C) mode of SECM is suitable to elucidate the possible reaction mechanisms and paths involved in the localize corrosion of stainless steel in neutral chloride solution. (C) 2009 Elsevier B. V. All rights reserved. |
原文出处 | |
公开日期 | 2012-04-13 |
源URL | [http://210.72.142.130/handle/321006/32508] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | Y. H. Yin,L. Niu,M. Lu,et al. In situ characterization of localized corrosion of stainless steel by scanning electrochemical microscope[J]. Applied Surface Science,2009,255(22):9193-9199. |
APA | Y. H. Yin,L. Niu,M. Lu,W. K. Guo,&S. H. Chen.(2009).In situ characterization of localized corrosion of stainless steel by scanning electrochemical microscope.Applied Surface Science,255(22),9193-9199. |
MLA | Y. H. Yin,et al."In situ characterization of localized corrosion of stainless steel by scanning electrochemical microscope".Applied Surface Science 255.22(2009):9193-9199. |
入库方式: OAI收割
来源:金属研究所
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