Fused thiophene-split oligothiophenes with high ionization potentials for OTFTs
文献类型:期刊论文
作者 | Y. Y. Zhang ; M. Ichikawa ; J. Hattori ; T. Kato ; A. Sazaki ; S. Kanazawa ; S. Kato ; C. H. Zhang ; Y. Taniguchi |
刊名 | Synthetic Metals
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出版日期 | 2009 |
卷号 | 159期号:17-18页码:1890-1895 |
关键词 | OTFT Fused thiophene Oligothiophene Ionization potential Air stability thin-film transistors field-effect transistors high-mobility organic semiconductors carrier mobility copolymers oligomers performance polymers |
ISSN号 | 0379-6779 |
中文摘要 | Fused thiophene-split oligothiophenes were synthesized by Suzuki coupling. The relationship between the structure of these fused thiophene-split oligothiophenes and DH-6T (alpha.omega-dihexylsexithiophene) and their performance in OTFTs was discussed. The realignment of HTTfTTTH (2,5-bis-(5'-hexyl-[2,2']bithiophenyl-5-yi)-thieno[3,2-b] thiophene) molecule on the substrate after annealing was revealed by X-ray diffraction and atomic force microscopy. A similar but novel compound, TTfTTT (2,5-bis[2,2']bithiophenyl-5-yl-thieno[3.2-blthiophene), was also prepared and evaluated as an organic transistor material. Air stabilities of these three compounds in OTFT devices were affected mainly by chemical properties, but also by the ionization potentials (I(p)) of these materials. Among the three compounds, HTTfTTTH had a higher I(p) because the thiophene sequence was split by fused thiophene and the best air stability, due to the end-capping of its active a-positions by hexyl substitution. (C) 2009 Elsevier B.V. All rights reserved. |
原文出处 | |
公开日期 | 2012-04-13 |
源URL | [http://210.72.142.130/handle/321006/32588] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | Y. Y. Zhang,M. Ichikawa,J. Hattori,et al. Fused thiophene-split oligothiophenes with high ionization potentials for OTFTs[J]. Synthetic Metals,2009,159(17-18):1890-1895. |
APA | Y. Y. Zhang.,M. Ichikawa.,J. Hattori.,T. Kato.,A. Sazaki.,...&Y. Taniguchi.(2009).Fused thiophene-split oligothiophenes with high ionization potentials for OTFTs.Synthetic Metals,159(17-18),1890-1895. |
MLA | Y. Y. Zhang,et al."Fused thiophene-split oligothiophenes with high ionization potentials for OTFTs".Synthetic Metals 159.17-18(2009):1890-1895. |
入库方式: OAI收割
来源:金属研究所
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