Characteristics of NiO-YSZ anode based on NiO particles synthesized by the precipitation method
文献类型：期刊论文
| 作者 | K. F. Chen ; Z. Lu ; X. J. Chen ; N. Ai ; X. Q. Huang ; B. Wei ; J. Y. Hu ; W. H. Su |
| 刊名 | Journal of Alloys and Compounds
 |
| 出版日期 | 2008 |
| 卷号 | 454期号:1-2页码:447-453 |
| 关键词 | SOFC NiO precipitation method NiO-YSZ anode porosity oxide fuel-cells intermediate temperature doped ceria performance cermets films microstructure polarization operation catalysts |
| ISSN号 | 0925-8388 |
| 中文摘要 | In order to increase the three phase boundary (TPB) length through lowering the NiO particles to submicro-size, NiO powder was synthesized by the precipitation method and the Corresponding NiO-YSZ (8 mol% yttria-stabilized zirconia) composite anodes were investigated in this paper. The crystallite size of the as-synthesized NiO particle was 20-30 nm. The particles were agglomerated, but the agglomerates could be partially broken by grinding. The powder has an average particle size of 0.36 mu m after grinding. NiO-YSZ anodes were fabricated by mixing the as-prepared NiO with commercial YSZ powders together. In order to form suitable porosity, flour was used as the pore-former, which played a key role in affecting the anode performance. Characteristics of the anodes, namely, shrinkage behavior, temperature-programmed reduction (TPR) measurement at a constant temperature (i.e., a modified TPR technique) and resistance characteristic during reduction were investigated. The maximum power density of the anode-supported YSZ film single cell was 905 mW/cm(2) at 750 degrees C based on the Anode-30 (NiO, YSZ and flour was mixed in the weight ratio of 5:5:3). As a summary, high cell performance could be achieved at reduced temperature with the as-fabricated NiO-YSZ anode containing a suitable microstructure. (C) 2007 Elsevier B.V. All rights reserved. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/32674]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | K. F. Chen,Z. Lu,X. J. Chen,et al. Characteristics of NiO-YSZ anode based on NiO particles synthesized by the precipitation method[J]. Journal of Alloys and Compounds,2008,454(1-2):447-453. |
| APA | K. F. Chen.,Z. Lu.,X. J. Chen.,N. Ai.,X. Q. Huang.,...&W. H. Su.(2008).Characteristics of NiO-YSZ anode based on NiO particles synthesized by the precipitation method.Journal of Alloys and Compounds,454(1-2),447-453. |
| MLA | K. F. Chen,et al."Characteristics of NiO-YSZ anode based on NiO particles synthesized by the precipitation method".Journal of Alloys and Compounds 454.1-2(2008):447-453. |
入库方式： OAI收割
来源：金属研究所
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