Local lattice structure of Mn(2+) ions in (MnO(6))(10-) coordination complex: Complete diagonalization of d(5) ions in a trigonal ligand field
文献类型：期刊论文
| 作者 | L. Cheng ; K. X. Yu ; Z. K. Wei |
| 刊名 | Materials Chemistry and Physics
 |
| 出版日期 | 2008 |
| 卷号 | 112期号:2页码:690-695 |
| 关键词 | Ligand field model Local structure (MnO(6))(10-) coordination complex hexa-antipyrine perchlorate optical-absorption magnetic-properties resonance spectra epr crystals transitions alpha-fe2o3 oxides iron |
| ISSN号 | 0254-0584 |
| 中文摘要 | A detailed theoretical method for studying the local lattice structure of Mn(2+) ions in (MnO(6))(10-) coordination complex is presented. Using the ligand field model, the formulas relating the microscopic spin Hamiltonian parameters with the crystal structure parameters are derived. Based on the theoretical formulas, the 252 x 252 complete energy matrices for d(5) configuration ions in a trigonal ligand field are constructed. By diagonalizing the complete energy matrices, the local structure distortion of Mn(2+) ions in A(C(11)H(12)ON(2))(6)(ClO(4))(2):Mn(2+) (A = Ca, Cd, Mg, Co, Pb) systems have been investigated. It is found that the theoretical results are in good agreement with the experimental values. (C) 2008 Elsevier B.V. All rights reserved. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/32689]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | L. Cheng,K. X. Yu,Z. K. Wei. Local lattice structure of Mn(2+) ions in (MnO(6))(10-) coordination complex: Complete diagonalization of d(5) ions in a trigonal ligand field[J]. Materials Chemistry and Physics,2008,112(2):690-695. |
| APA | L. Cheng,K. X. Yu,&Z. K. Wei.(2008).Local lattice structure of Mn(2+) ions in (MnO(6))(10-) coordination complex: Complete diagonalization of d(5) ions in a trigonal ligand field.Materials Chemistry and Physics,112(2),690-695. |
| MLA | L. Cheng,et al."Local lattice structure of Mn(2+) ions in (MnO(6))(10-) coordination complex: Complete diagonalization of d(5) ions in a trigonal ligand field".Materials Chemistry and Physics 112.2(2008):690-695. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。