Theoretical study of local lattice structure of (FeOF5)(4-) cluster in diamagnetic pervoskite RbCdF3
文献类型：期刊论文
| 作者 | M. L. Duan ; X. Y. Kuang ; J. H. Li ; Z. Y. Jiao |
| 刊名 | Molecular Physics
 |
| 出版日期 | 2008 |
| 卷号 | 106期号:5页码:723-728 |
| 关键词 | local structure complete energy matrix (FeOF5)(4-) cluster EPR spin-hamiltonian parameters electron-paramagnetic-res epr investigations resonance coordination crystals spectra ions perovskites complexes |
| ISSN号 | 0026-8976 |
| 中文摘要 | A theoretical method for studying the local structure of a doped system has been established on the basis of a 252 x 252 complete energy matrix in a tetragonal ligand-field. By analysing the EPR spectrum of an (FeOF5)(4-) cluster in diamagnetic perovskites RbCdF3, the local structure parameters R-1 and R-2 of RbCdF3 crystal, doped with iron ion, has been determined using a more sensitive (FeOF5)(4-) than (FeF6)(3-) cluster as a probe. The calculations can be reasonably explained by electrostatic interaction and simultaneously can provide a satisfactory explanation of the large EPR parameter b(2)(0) |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/32729]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | M. L. Duan,X. Y. Kuang,J. H. Li,et al. Theoretical study of local lattice structure of (FeOF5)(4-) cluster in diamagnetic pervoskite RbCdF3[J]. Molecular Physics,2008,106(5):723-728. |
| APA | M. L. Duan,X. Y. Kuang,J. H. Li,&Z. Y. Jiao.(2008).Theoretical study of local lattice structure of (FeOF5)(4-) cluster in diamagnetic pervoskite RbCdF3.Molecular Physics,106(5),723-728. |
| MLA | M. L. Duan,et al."Theoretical study of local lattice structure of (FeOF5)(4-) cluster in diamagnetic pervoskite RbCdF3".Molecular Physics 106.5(2008):723-728. |
入库方式： OAI收割
来源：金属研究所
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