中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Isothermal oxidation of bulk Zr(2)Al(3)C(4) at 500 to 1000 degrees C in air

文献类型:期刊论文

作者L. F. He ; Z. J. Lin ; Y. W. Bao ; M. S. Li ; J. Y. Wang ; Y. C. Zhou
刊名Journal of Materials Research
出版日期2008
卷号23期号:2页码:359-366
ISSN号0884-2914
关键词high-temperature oxidation zirconium carbide behavior kinetics ti2alc zr
中文摘要The isothermal oxidation behavior of Zr(2)Al(3)C(4) in the temperature range of 500 to 1000 inverted perpendicular C for 20 h in air has been investigated. The oxidation kinetics follow a parabolic law at 600 to 800 degrees C and a linear law at higher temperatures. The activation energy is determined to be 167.4 and 201.2 kJ/mol at parabolic and linear stages, respectively. The oxide scales have a monolayer structure, which is a mixture of ZrO(2) and Al(2)O(3). As indicated by x-ray diffraction and Raman spectra, the scales formed at 500 to 700 degrees C are amorphous, and at higher temperatures are alpha-Al(2)O(3), and t-ZrO(2) nanocrystallites. The nonselective oxidation of Zr(2)Al(3)C(4) can be attributed to the strong coupling between Al(3)C(2) units and ZrC blocks in its structure, and the close oxygen affinity of Zr and Al.
原文出处://WOS:000253010800010
公开日期2012-04-13
源URL[http://210.72.142.130/handle/321006/32802]  
专题金属研究所_中国科学院金属研究所
推荐引用方式
GB/T 7714
L. F. He,Z. J. Lin,Y. W. Bao,et al. Isothermal oxidation of bulk Zr(2)Al(3)C(4) at 500 to 1000 degrees C in air[J]. Journal of Materials Research,2008,23(2):359-366.
APA L. F. He,Z. J. Lin,Y. W. Bao,M. S. Li,J. Y. Wang,&Y. C. Zhou.(2008).Isothermal oxidation of bulk Zr(2)Al(3)C(4) at 500 to 1000 degrees C in air.Journal of Materials Research,23(2),359-366.
MLA L. F. He,et al."Isothermal oxidation of bulk Zr(2)Al(3)C(4) at 500 to 1000 degrees C in air".Journal of Materials Research 23.2(2008):359-366.

入库方式: OAI收割

来源:金属研究所

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