Investigation of optical spectra and local structure for (CrF(6))(3-) cluster in Cs(2)NaAlF(6): Cr(3+) and Cs(2)NaGaF(6): Cr(3+) systems
文献类型：期刊论文
| 作者 | J. L. Huang ; X. Y. Kuang ; Y. Li |
| 刊名 | Chemical Physics Letters
 |
| 出版日期 | 2008 |
| 卷号 | 458期号:1-3页码:227-230 |
| 关键词 | electron-paramagnetic-resonance symmetry-based equivalence angular-overlap models single-crystals hexagonal elpasolites cr3+ ions spectroscopy field fluorides state |
| ISSN号 | 0009-2614 |
| 中文摘要 | To investigate the local structure of the (CrF(6))(3) cluster for Cr(3+) in Cs(2)NaAlF(6) and Cs(2)NaGaF(6), the unified calculations of the whole EPR, optical spectra are made based on the 120 x 120 complete energy matrices which are constructed on the basis of the complete set of the basis vertical bar J, M(J)>. The results demonstrate that Cr(3+) substitute for the two inequivalent M(3+) sites rather than the Na(+) or Cs(+), which accord with the conclusion of several experiments. Simultaneously, the local structure parameters are determined and the relationship between the structure and the temperature has been discussed. (C) 2008 Elsevier B.V. All rights reserved. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/32830]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | J. L. Huang,X. Y. Kuang,Y. Li. Investigation of optical spectra and local structure for (CrF(6))(3-) cluster in Cs(2)NaAlF(6): Cr(3+) and Cs(2)NaGaF(6): Cr(3+) systems[J]. Chemical Physics Letters,2008,458(1-3):227-230. |
| APA | J. L. Huang,X. Y. Kuang,&Y. Li.(2008).Investigation of optical spectra and local structure for (CrF(6))(3-) cluster in Cs(2)NaAlF(6): Cr(3+) and Cs(2)NaGaF(6): Cr(3+) systems.Chemical Physics Letters,458(1-3),227-230. |
| MLA | J. L. Huang,et al."Investigation of optical spectra and local structure for (CrF(6))(3-) cluster in Cs(2)NaAlF(6): Cr(3+) and Cs(2)NaGaF(6): Cr(3+) systems".Chemical Physics Letters 458.1-3(2008):227-230. |
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来源：金属研究所
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