Spin-Hamiltonian parameters and defect structure for Co(4+) in Al(2)O(3):Mg(2+) crystal
文献类型:期刊论文
作者 | G. M. Jia ; L. He ; W. C. Zheng |
刊名 | Physica B-Condensed Matter
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出版日期 | 2008 |
卷号 | 403期号:21-22页码:3950-3952 |
关键词 | Electron paramagnetic resonance Defect structure Crystal-field theory Co(4+) Al(2)O(3) paramagnetic-resonance optical spectra pressure ions epr impurities ruby alpha-al2o3 insulators fields |
ISSN号 | 0921-4526 |
中文摘要 | The spin-Hamiltonian parameters (g factors g(parallel to), g(perpendicular to) and hyperfine structure constants A(parallel to) and A(perpendicular to)) for Co(4+) ion in Al(2)O(3):Mg(2+) crystals are calculated from the resonance theory related to the low-spin (2)T(2) term in trigonal symmetry. The calculated values are in reasonable agreement with the observed values. From the calculation, the defect structure of Co(4+) Center in Al(2)O(3): Mg2+ crystal is obtained. The result is consistent with the expectations based on the electrostatic interaction and electron cloud overlap. The signs of hyperfine structure constants A(parallel to) and A(perpendicular to) are suggested. (C) 2008 Elsevier B.V. All rights reserved. |
原文出处 | |
公开日期 | 2012-04-13 |
源URL | [http://210.72.142.130/handle/321006/32843] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | G. M. Jia,L. He,W. C. Zheng. Spin-Hamiltonian parameters and defect structure for Co(4+) in Al(2)O(3):Mg(2+) crystal[J]. Physica B-Condensed Matter,2008,403(21-22):3950-3952. |
APA | G. M. Jia,L. He,&W. C. Zheng.(2008).Spin-Hamiltonian parameters and defect structure for Co(4+) in Al(2)O(3):Mg(2+) crystal.Physica B-Condensed Matter,403(21-22),3950-3952. |
MLA | G. M. Jia,et al."Spin-Hamiltonian parameters and defect structure for Co(4+) in Al(2)O(3):Mg(2+) crystal".Physica B-Condensed Matter 403.21-22(2008):3950-3952. |
入库方式: OAI收割
来源:金属研究所
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