Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal Ni(H2O)(6) (2)+ Cluster in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O Crystals at Different Temperatures
文献类型：期刊论文
| 作者 | H. F. Li ; X. Y. Kuang ; H. Q. Wang ; A. J. Mao |
| 刊名 | Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences
 |
| 出版日期 | 2008 |
| 卷号 | 63期号:9页码:609-615 |
| 关键词 | Local Structure Orbital Reduction Effect EPR Spectrum Complete Energy Matrices electron-paramagnetic-resonance nickel fluosilicate spectra zinc |
| ISSN号 | 0932-0784 |
| 中文摘要 | The local octahedral environment of Ni2+ in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O crystals with a trigonal distortion has been studied at different temperatures, based on the complete energy matrices. The calculated results showed that the local lattice structure around an octahedral Ni2+ centre in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O exhibits at compression distortion. Simultaneously, the orbital reduction effect on the g factors has been studied. The relationship between Ag =g(parallel to) -g(perpendicular to) and orbital reduction fractor k at 4.2.77 and 298 (302) K has been discussed. suggesting, that there is an almost linear relation between k and Delta g in Ni2+ ion in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O at each temperature. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/32865]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | H. F. Li,X. Y. Kuang,H. Q. Wang,et al. Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal Ni(H2O)(6) (2)+ Cluster in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O Crystals at Different Temperatures[J]. Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,2008,63(9):609-615. |
| APA | H. F. Li,X. Y. Kuang,H. Q. Wang,&A. J. Mao.(2008).Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal Ni(H2O)(6) (2)+ Cluster in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O Crystals at Different Temperatures.Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,63(9),609-615. |
| MLA | H. F. Li,et al."Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal Ni(H2O)(6) (2)+ Cluster in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O Crystals at Different Temperatures".Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences 63.9(2008):609-615. |
入库方式： OAI收割
来源：金属研究所
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