Local defect structures and EPR studies on (FeO6)9-and (FeO4)5-clusters in YGG: Fe3+system
文献类型:期刊论文
作者 | H. L. Li ; X. Y. Kuang ; Y. Li ; M. L. Duan |
刊名 | Molecular Physics
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出版日期 | 2008 |
卷号 | 106期号:21-23页码:2643-2648 |
关键词 | EPR local defect structure Fe3+centres spin-hamiltonian parameters theoretical investigations paramagnetic resonance garnet structure crystals centers cr3+ ion spectroscopy absorption |
ISSN号 | 0026-8976 |
中文摘要 | The octahedral (FeO6)9- and tetrahedral (FeO4)5- clusters in yttrium gallium garnet (YGG): Fe3+ system are investigated based on the 252 252 complete energy matrices for d5 configuration ions in trigonal and tetragonal ligand fields, moreover, the EPR and optical spectra are made unified calculation. The results indicate that the defect structures around Fe3+ centres display expansion effects at different temperatures 4.2 and 295 K, and which are close to those in YIG garnet, respectively. Simultaneously, the defect structure parameters for Fe3+ centres in YGG are determined, and the relationship between the defect structure and the temperature has been discussed. |
原文出处 | |
公开日期 | 2012-04-13 |
源URL | [http://210.72.142.130/handle/321006/32866] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | H. L. Li,X. Y. Kuang,Y. Li,et al. Local defect structures and EPR studies on (FeO6)9-and (FeO4)5-clusters in YGG: Fe3+system[J]. Molecular Physics,2008,106(21-23):2643-2648. |
APA | H. L. Li,X. Y. Kuang,Y. Li,&M. L. Duan.(2008).Local defect structures and EPR studies on (FeO6)9-and (FeO4)5-clusters in YGG: Fe3+system.Molecular Physics,106(21-23),2643-2648. |
MLA | H. L. Li,et al."Local defect structures and EPR studies on (FeO6)9-and (FeO4)5-clusters in YGG: Fe3+system".Molecular Physics 106.21-23(2008):2643-2648. |
入库方式: OAI收割
来源:金属研究所
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