中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
An investigation on general corrosion and pitting of iron with the in-line digital holography

文献类型:期刊论文

作者L. Li ; C. Wang ; S. H. Chen ; X. G. Yang ; B. Y. Yuan ; H. L. Jia
刊名Electrochimica Acta
出版日期2008
卷号53期号:7页码:3109-3119
关键词digital holography general corrosion pitting iron temporal structure spatial structure point-defect model sulfuric-acid-solution anodic passive films current oscillations stainless-steels fitting corrosion magnetic-field oxide-films aluminum breakdown
ISSN号0013-4686
中文摘要In the anodic processes of the iron electrode in both neutral and acidic solutions, general corrosion and pitting dynamical processes in the presence of chloride ions were observed in situ with the in-line digital holography. The dynamic processes such as formation and dissolution of the passive film, initiation and propagation of pitting have been studied. During the general corrosion, not only is the temporal structure in order, evidenced by the regular change of current with time, but also the spatial structure, indicated by the uniform fringes in the holograms at the electrode/electrolyte interface. However, during the pitting processes, the order of the spatial structure is destroyed, which is indicated by the wrinkled fringes in the holograms; the temporal order is broken as well evidenced by the irregular change of current with time. The experimental result shows that there is synergistic effect between H+ and Cl- on both the initiation stage and the propagation stage. With the presence of chloride ions, pitting occurs much more easily in acidic solution than in neutral solution. (C) 2007 Elsevier Ltd. All rights reserved.
原文出处://WOS:000253804300012
公开日期2012-04-13
源URL[http://210.72.142.130/handle/321006/32879]  
专题金属研究所_中国科学院金属研究所
推荐引用方式
GB/T 7714
L. Li,C. Wang,S. H. Chen,et al. An investigation on general corrosion and pitting of iron with the in-line digital holography[J]. Electrochimica Acta,2008,53(7):3109-3119.
APA L. Li,C. Wang,S. H. Chen,X. G. Yang,B. Y. Yuan,&H. L. Jia.(2008).An investigation on general corrosion and pitting of iron with the in-line digital holography.Electrochimica Acta,53(7),3109-3119.
MLA L. Li,et al."An investigation on general corrosion and pitting of iron with the in-line digital holography".Electrochimica Acta 53.7(2008):3109-3119.

入库方式: OAI收割

来源:金属研究所

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