Investigation of hydrogen absorption/desorption properties of ZrMn0.85-xFe1+x alloys
文献类型：期刊论文
| 作者 | S. L. Li ; H. H. Cheng ; X. X. Deng ; W. Chen ; D. M. Chen ; K. Yang |
| 刊名 | Journal of Alloys and Compounds
 |
| 出版日期 | 2008 |
| 卷号 | 460期号:1-2页码:186-190 |
| 关键词 | hydrogen absorbing materials metal hydrides gas-solid reactions thermodynamic properties thermodynamic properties storage characteristics absorption hydrides systems stability zrmn2 |
| ISSN号 | 0925-8388 |
| 中文摘要 | The crystal structures and hydrogen absorption/desorption properties of the ZrMn0.85-xFe1+x alloys (x = 0, 0.2, 0.4) were investigated systematically. The pressure-composition (PC) isotherms and absorption kinetics were measured at 273-333 K by the volumetric method. Besides the crystal structure, the plateau pressure and the hydrogen intake capacity, this article also discussed the absorption kinetics, the pulverization resistance and the thermodynamic properties. XRD patterns revealed that ZrMn0.85Fe and ZrMn0.65Fe1.2 were formed as hexagonal C14 laves phase structure while ZrMn0.45Fe1.4 possessed cubic C15 laves phase structure. With the increase of Fe and decrease of Mn, the plateau pressure increased while the hydrogen intake capacity lowered and the hydrogen absorption kinetics degraded. On the other hand, the hysteresis alleviated, the pulverization resistance improved and the stability of the hydrides decreased. The decomposition pressure was increased to more than 160 times for ZrMn0.85Fe and more than 2500 times for ZrMn0.65Fe1.2 compared with that of the ZrMn2 alloy. (C) 2007 Elsevier B.V. All rights reserved. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/32892]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | S. L. Li,H. H. Cheng,X. X. Deng,et al. Investigation of hydrogen absorption/desorption properties of ZrMn0.85-xFe1+x alloys[J]. Journal of Alloys and Compounds,2008,460(1-2):186-190. |
| APA | S. L. Li,H. H. Cheng,X. X. Deng,W. Chen,D. M. Chen,&K. Yang.(2008).Investigation of hydrogen absorption/desorption properties of ZrMn0.85-xFe1+x alloys.Journal of Alloys and Compounds,460(1-2),186-190. |
| MLA | S. L. Li,et al."Investigation of hydrogen absorption/desorption properties of ZrMn0.85-xFe1+x alloys".Journal of Alloys and Compounds 460.1-2(2008):186-190. |
入库方式： OAI收割
来源：金属研究所
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