Investigation of local lattice structure around Cr(3+) ions at the trigonal and tetragonal sites in RbCdF(3): Cr(3+) crystal
文献类型：期刊论文
| 作者 | A. J. Mao ; X. Y. Kuang |
| 刊名 | Molecular Physics
 |
| 出版日期 | 2008 |
| 卷号 | 106期号:8页码:1033-1038 |
| 关键词 | complete energy matrices d3 EPR and optical spectra 7 ions local structure trigonal and tetragonal sites phase-transition field spectra epr-spectra centers |
| ISSN号 | 0026-8976 |
| 中文摘要 | The local lattice structure and EPR, optical spectra for Cr(3+) doped in RbCdF(3) crystal have been studied by diagonalizing the complete energy matrices. The results show that the local structure of the Cr(3+) ions in RbCdF(3) exhibits a compressed distortion at the trigonal and tetragonal sites. The compressed distortion can be ascribed to the fact that the radius of Cr(3+) ion is smaller than that of Cd(2+) ion, and therefore Cr(3+) ion will draw the fluorin ligands inwards. The variational ranges of the local structural parameters for Cr(3+) doped in RbCdF(3) crystal R = 1.9491 angstrom similar to 1.9814 angstrom, theta = 55.234 degrees similar to 55.286 degrees at the trigonal site and R(1) = 1.8617 angstrom similar to 1.8928 angstrom, R(2) = 1.9527 angstrom similar to 1.9851 angstrom at tetragonal site are obtained respectively, and the EPR and optical spectra agree well with the experimental results. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/33028]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | A. J. Mao,X. Y. Kuang. Investigation of local lattice structure around Cr(3+) ions at the trigonal and tetragonal sites in RbCdF(3): Cr(3+) crystal[J]. Molecular Physics,2008,106(8):1033-1038. |
| APA | A. J. Mao,&X. Y. Kuang.(2008).Investigation of local lattice structure around Cr(3+) ions at the trigonal and tetragonal sites in RbCdF(3): Cr(3+) crystal.Molecular Physics,106(8),1033-1038. |
| MLA | A. J. Mao,et al."Investigation of local lattice structure around Cr(3+) ions at the trigonal and tetragonal sites in RbCdF(3): Cr(3+) crystal".Molecular Physics 106.8(2008):1033-1038. |
入库方式： OAI收割
来源：金属研究所
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