Thermodynamics Theory for Sol-gel Transition of Branched Polymers
文献类型：期刊论文
| 作者 | H. J. Wang ; J. J. Liu ; X. W. Ba |
| 刊名 | Chemical Journal of Chinese Universities-Chinese
 |
| 出版日期 | 2008 |
| 卷号 | 29期号:12页码:2474-2478 |
| 关键词 | Equilibrium free energy Law of mass action Size distribution Sol-gel phase transition molecular-size distribution thermoreversible gelation junctions |
| ISSN号 | 0251-0790 |
| 中文摘要 | Several equilibrium properties of typical polycondensation system of A(a)-B(b) type were studied by the principle of statistical thermodynamics. Starting with the canonical partition functions constructed from two viewpoints, the explicit expressions of the equilibrium free energy and the law of mass action are obtained. Meanwhile, two new methods were proposed to derive the equilibrium size distribution, and the gelation condition was carried out by the isothermal compressibility. Furthermore, based on the invariant property of the equilibrium size distribution, the equilibrium free energies of sol and gel phases in postgel regime were given, and the relevant issues on the sol-gel phase transition were discussed. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/33127]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | H. J. Wang,J. J. Liu,X. W. Ba. Thermodynamics Theory for Sol-gel Transition of Branched Polymers[J]. Chemical Journal of Chinese Universities-Chinese,2008,29(12):2474-2478. |
| APA | H. J. Wang,J. J. Liu,&X. W. Ba.(2008).Thermodynamics Theory for Sol-gel Transition of Branched Polymers.Chemical Journal of Chinese Universities-Chinese,29(12),2474-2478. |
| MLA | H. J. Wang,et al."Thermodynamics Theory for Sol-gel Transition of Branched Polymers".Chemical Journal of Chinese Universities-Chinese 29.12(2008):2474-2478. |
入库方式： OAI收割
来源：金属研究所
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