Theoretical study of the superhyperfine parameters for Cu(2+) in K(2)PdX(4) (X = Cl, Br)
文献类型：期刊论文
| 作者 | L. H. Wei ; S. Y. Wu ; Z. H. Zhang ; X. F. Wang ; Y. X. Hu |
| 刊名 | Hyperfine Interactions
 |
| 出版日期 | 2008 |
| 卷号 | 181期号:1-3页码:169-177 |
| 关键词 | Electron paramagnetic resonance (EPR) K(2)PdX(4) (X = Cl Superhyperfine interactions Br) Cu(2+) atomic screening constants square-planar angular distortions liquid-membrane scf functions absorption k2pdcl4 spectra complexes carrier |
| ISSN号 | 0304-3843 |
| 中文摘要 | The superhyperfine parameters T(j) (j = x, y, z) for Cu(2+) in the square-planar K(2)PdX(4) (X = Cl, Br) are theoretically studied from the perturbation formulas of these parameters for an octahedral 3d(9) cluster, by considering both the contributions from the crystal-field and charge-transfer mechanisms. The related molecular orbital coefficients are determined from the cluster approach in a uniform way. Based on one adjustable proportional factor rho for the orbital admixture coefficients, the calculated results of present work show reasonable agreement with the observed values. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/33185]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | L. H. Wei,S. Y. Wu,Z. H. Zhang,et al. Theoretical study of the superhyperfine parameters for Cu(2+) in K(2)PdX(4) (X = Cl, Br)[J]. Hyperfine Interactions,2008,181(1-3):169-177. |
| APA | L. H. Wei,S. Y. Wu,Z. H. Zhang,X. F. Wang,&Y. X. Hu.(2008).Theoretical study of the superhyperfine parameters for Cu(2+) in K(2)PdX(4) (X = Cl, Br).Hyperfine Interactions,181(1-3),169-177. |
| MLA | L. H. Wei,et al."Theoretical study of the superhyperfine parameters for Cu(2+) in K(2)PdX(4) (X = Cl, Br)".Hyperfine Interactions 181.1-3(2008):169-177. |
入库方式： OAI收割
来源：金属研究所
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