New theoretical method for studying polycondensation of A(a) type
文献类型：期刊论文
| 作者 | Z. F. Zhao ; H. J. Wang |
| 刊名 | Chemical Journal of Chinese Universities-Chinese
 |
| 出版日期 | 2008 |
| 卷号 | 29期号:4页码:805-808 |
| 关键词 | equilibrium free energy law of mass action sol-gel phase transition molecular-size distribution thermoreversible gelation gel formation polymers junctions |
| ISSN号 | 0251-0790 |
| 中文摘要 | The canonical partition functions of polycondensation of A(a) type were constructed from two viewpoints by the principle of statistical mechanics, and the explicit expressions of the equilibrium free energy and the law of mass action were obtained. Meanwhile, two new methods were used to derive the number fraction distribution function. Below the critical point of the sol-gel transition, the equilibrium free energy of sol and gel phases were given on the basis of the intrinsic invariant property of the number faction distribution function. Furthermore, the sol-gel phase transition is shown to be a kind of geometric phase transition rather than thermodynamic phase transition. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/33375]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | Z. F. Zhao,H. J. Wang. New theoretical method for studying polycondensation of A(a) type[J]. Chemical Journal of Chinese Universities-Chinese,2008,29(4):805-808. |
| APA | Z. F. Zhao,&H. J. Wang.(2008).New theoretical method for studying polycondensation of A(a) type.Chemical Journal of Chinese Universities-Chinese,29(4),805-808. |
| MLA | Z. F. Zhao,et al."New theoretical method for studying polycondensation of A(a) type".Chemical Journal of Chinese Universities-Chinese 29.4(2008):805-808. |
入库方式： OAI收割
来源：金属研究所
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