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AC impedance spectroscopy study of the corrosion behavior of an AZ91 magnesium alloy in 0.1 M sodium sulfate solution

文献类型:期刊论文

作者J. Chen ; J. Q. Wang ; E. H. Han ; J. H. Dong ; W. Ke
刊名Electrochimica Acta
出版日期2007
卷号52期号:9页码:3299-3309
关键词AZ91 magnesium alloy sodium sulfate corrosion EIS ESEM chloride
ISSN号0013-4686
中文摘要The corrosion behavior of an AZ91 magnesium alloy in 0.1 M sodium sulfate solution at the corrosion potential (E-corr) was investigated using electrochemical impedance spectroscopy (EIS), environmental scanning electron microscopy (ESEM), energy dispersive X-ray spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS). The results showed that when the immersion time was less than 18th, general corrosion occurred on the surface and the main corrosion products were hydroxides and sulfates. The film coverage effect was the main mechanism for the corrosion process of AZ91 alloy. At this stage, the matrix had a better corrosion resistance. With the increasing immersion time, pitting occurred on the surface. At this stage, the corrosion process was controlled by three surface state variables: the area fraction theta(1) of the region controlled by the formation of Mg(OH)(2), the area fraction theta(2) of the region controlled by the precipitation of MgAl2(SO4)(4).2H(2)O, and the metastable Mg+ concentration C.. (c) 2006 Elsevier Ltd. All rights reserved.
原文出处://WOS:000244585200047
公开日期2012-04-13
源URL[http://ir.imr.ac.cn/handle/321006/33447]  
专题金属研究所_中国科学院金属研究所
推荐引用方式
GB/T 7714
J. Chen,J. Q. Wang,E. H. Han,et al. AC impedance spectroscopy study of the corrosion behavior of an AZ91 magnesium alloy in 0.1 M sodium sulfate solution[J]. Electrochimica Acta,2007,52(9):3299-3309.
APA J. Chen,J. Q. Wang,E. H. Han,J. H. Dong,&W. Ke.(2007).AC impedance spectroscopy study of the corrosion behavior of an AZ91 magnesium alloy in 0.1 M sodium sulfate solution.Electrochimica Acta,52(9),3299-3309.
MLA J. Chen,et al."AC impedance spectroscopy study of the corrosion behavior of an AZ91 magnesium alloy in 0.1 M sodium sulfate solution".Electrochimica Acta 52.9(2007):3299-3309.

入库方式: OAI收割

来源:金属研究所

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