Application of the adsorption potential theory to hydrogen adsorption on zeolites above critical temperature
文献类型:期刊论文
作者 | X. M. Du ; E. D. Wu |
刊名 | Acta Physico-Chimica Sinica
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出版日期 | 2007 |
卷号 | 23期号:6页码:813-819 |
关键词 | adsorption potential theory hydrogen zeolites generalized adsorption function affinity coefficients high-pressure physical adsorption supercritical gases adsorbents equation isotherms methane vapors |
ISSN号 | 1000-6818 |
中文摘要 | The adsorption potential theory was applied to study the adsorption isotherms of hydrogen on four kinds of zeolites above critical temperature and under a wide range of pressure. An approximate treatment was used to obtain the pseudo-saturated pressure of supercritical hydrogen and the affinity coefficients of adsorption systems under study. A formula for the generalized adsorption function to describe supercritical adsorption of hydrogen on zeolites was derived by the analysis of the functional dependence of the adsorption amount on the adsorption potential and the affinity coefficients. The study showed that the affinity coefficients had a linear relation with the adsorption heat, which could be used as a parameter of the generalized adsorption function in characterization of an adsorption system. The fittings of the generalized adsorption function to experimental data exhibited that the hydrogen adsorption on zeolites above critical temperature could be satisfactorily described by the generalized adsorption function. |
原文出处 | |
公开日期 | 2012-04-13 |
源URL | [http://ir.imr.ac.cn/handle/321006/33506] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | X. M. Du,E. D. Wu. Application of the adsorption potential theory to hydrogen adsorption on zeolites above critical temperature[J]. Acta Physico-Chimica Sinica,2007,23(6):813-819. |
APA | X. M. Du,&E. D. Wu.(2007).Application of the adsorption potential theory to hydrogen adsorption on zeolites above critical temperature.Acta Physico-Chimica Sinica,23(6),813-819. |
MLA | X. M. Du,et al."Application of the adsorption potential theory to hydrogen adsorption on zeolites above critical temperature".Acta Physico-Chimica Sinica 23.6(2007):813-819. |
入库方式: OAI收割
来源:金属研究所
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