Structural and magnetic properties of chemically synthesized Sn1-xMnxO2 nanocrystalline powders
文献类型:期刊论文
作者 | L. B. Duan ; G. H. Rao ; J. Yu ; Y. C. Wang ; G. Y. Liu ; J. K. Liang |
刊名 | Journal of Applied Physics
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出版日期 | 2007 |
卷号 | 101期号:6 |
关键词 | room-temperature ferromagnetism doped sno2 semiconductors transition zno mn co oxides films bulk |
ISSN号 | 0021-8979 |
中文摘要 | Sn1-xMnxO2 nanocrystalline powders were synthesized by a wet chemical method (x <= 0.08). X-ray diffraction reveals that single-phase rutile Sn1-xMnxO2 was obtained for x up to about 0.06. Evolution of cell parameters, x-ray photoelectron spectroscopy measurements, thermogravimetric analysis, and quantitative evaluation of the magnetization data all indicate that Mn element acts as Mn4+ for x=0.01 and as Mn3+ for x=0.02 and 0.04 at room temperature, but as Mn3+ for all the samples at 5 K. Magnetization data show that the average magnetic moment per Mn site decreases with increasing x at 5 K, while the effective fraction of the Mn ions contributing to the magnetization decreases. The magnetic properties of the Sn1-xMnxO2 are discussed based on the competition between the free carrier mediated Ruderman-Kittel-Kasuya-Yosida interaction and antiferromagnetic superexchange interaction in the system. (c) 2007 American Institute of Physics. |
原文出处 | |
公开日期 | 2012-04-13 |
源URL | [http://ir.imr.ac.cn/handle/321006/33511] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | L. B. Duan,G. H. Rao,J. Yu,et al. Structural and magnetic properties of chemically synthesized Sn1-xMnxO2 nanocrystalline powders[J]. Journal of Applied Physics,2007,101(6). |
APA | L. B. Duan,G. H. Rao,J. Yu,Y. C. Wang,G. Y. Liu,&J. K. Liang.(2007).Structural and magnetic properties of chemically synthesized Sn1-xMnxO2 nanocrystalline powders.Journal of Applied Physics,101(6). |
MLA | L. B. Duan,et al."Structural and magnetic properties of chemically synthesized Sn1-xMnxO2 nanocrystalline powders".Journal of Applied Physics 101.6(2007). |
入库方式: OAI收割
来源:金属研究所
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