Theoretical studies of the spin-Hamiltonian parameters and the effects of the temperature and pressure on the zero-field splitting for Ni2+: Zn(BF4)(2) center dot 6H(2)O crystal
文献类型：期刊论文
| 作者 | W. L. Feng ; W. C. Zheng ; X. X. Wu ; H. G. Liu |
| 刊名 | Physica B-Condensed Matter
 |
| 出版日期 | 2007 |
| 卷号 | 387期号:1-2页码:52-55 |
| 关键词 | EPR spectra defect structure crystal-field theory effect of pressure and temperature Ni2+ Zn(BF4)(2) center dot 6H(2)O electron-paramagnetic-resonance phase-transitions superposition model epr-spectrum dependence ions impurities stress co2+ cr3+ |
| ISSN号 | 0921-4526 |
| 中文摘要 | The spin-Hamiltonian parameters (the g factors g(parallel to), g(perpendicular to) and the zero-field splitting D) and the effects of the temperature and pressure on D for Ni2+ ion at the trigonal Zri(2+) site in the low- and room-temperature phase of Zn(BF4)(2) (.) 6H(2)O crystal are calculated. The calculations are based on the microscopic spin Hamiltonian theory in teams of the diagonalization. of the complete energy matrix of 3d(8) ions in trigonal symmetry. The crystal-field parameters related to the impurity structure are obtained from the superposition model. Thus, the local trigonal distortion angle theta, the local angular thermal expansion coefficient and local angular compressibility for Ni2+ impurity centers in Zn(BF4)(2) (.) 6H(2)O crystal are estimated. The reasonableness of these local values is discussed. (c) 2006 Elsevier B.V. All rights reserved. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/33534]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | W. L. Feng,W. C. Zheng,X. X. Wu,et al. Theoretical studies of the spin-Hamiltonian parameters and the effects of the temperature and pressure on the zero-field splitting for Ni2+: Zn(BF4)(2) center dot 6H(2)O crystal[J]. Physica B-Condensed Matter,2007,387(1-2):52-55. |
| APA | W. L. Feng,W. C. Zheng,X. X. Wu,&H. G. Liu.(2007).Theoretical studies of the spin-Hamiltonian parameters and the effects of the temperature and pressure on the zero-field splitting for Ni2+: Zn(BF4)(2) center dot 6H(2)O crystal.Physica B-Condensed Matter,387(1-2),52-55. |
| MLA | W. L. Feng,et al."Theoretical studies of the spin-Hamiltonian parameters and the effects of the temperature and pressure on the zero-field splitting for Ni2+: Zn(BF4)(2) center dot 6H(2)O crystal".Physica B-Condensed Matter 387.1-2(2007):52-55. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。