Electrosynthesis and crystal structure of K3Na(FeO4)(2)
文献类型：期刊论文
| 作者 | W. C. He ; X. R. Hu ; B. C. Shen ; Z. Tang ; J. M. Wang ; J. Q. Zhang |
| 刊名 | Chinese Journal of Inorganic Chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 23期号:4页码:655-658 |
| 关键词 | K3Na(FeO4)(2) XRD structure analysis electrosynthesis electrochemical performance physical-properties charge-transfer ferrate iron electrode k2feo4 cathodes |
| ISSN号 | 1001-4861 |
| 中文摘要 | It is reported in this paper for the indirect electrosynthesis of a mixed ferrate(V) crystal, K3Na(FeO4)(2), with a comparatively high purity and its crystal structure is investigated in detail by powders XRD structure analysis. Its chemical formula is ascertained by EDX and AAS. The structure analysis showed that the crystal of K3Na(FeO4)(2) is of hexagonal unit cell, space group P3ml (164), Z=1, 6 atoms of O are located at 6 (i) Wyckoff Sites, 2 atoms of O, Fe and K at 2 (d), respectively, 1 atom of K and Na at 1 (b) and 1 (a), respectively. Cell parameters a=0.5 33 3(1) rim, c=0.755 9(1) nm,D=2.824 g center dot cm(-3). And all inter-atomic distances of K3Na(FeO4)(2) are obtained. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/33576]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | W. C. He,X. R. Hu,B. C. Shen,et al. Electrosynthesis and crystal structure of K3Na(FeO4)(2)[J]. Chinese Journal of Inorganic Chemistry,2007,23(4):655-658. |
| APA | W. C. He,X. R. Hu,B. C. Shen,Z. Tang,J. M. Wang,&J. Q. Zhang.(2007).Electrosynthesis and crystal structure of K3Na(FeO4)(2).Chinese Journal of Inorganic Chemistry,23(4),655-658. |
| MLA | W. C. He,et al."Electrosynthesis and crystal structure of K3Na(FeO4)(2)".Chinese Journal of Inorganic Chemistry 23.4(2007):655-658. |
入库方式： OAI收割
来源：金属研究所
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