Study on the synthesis and physicochemistry properties of tripotassium sodium Ferrate(VI)
文献类型：期刊论文
| 作者 | W. C. He ; J. M. Wang ; L. Zhou ; Q. Q. Chen ; B. C. Shen ; J. Q. Zhang |
| 刊名 | Acta Chimica Sinica
 |
| 出版日期 | 2007 |
| 卷号 | 65期号:20页码:2261-2265 |
| 关键词 | tripotassium sodium ferrate(VI) sodium ferrate(VI) electrosynthesis IR spectra XRD TG/DSC electrochemical performance charge-transfer iron k2feo4 generation electrode stability cathodes |
| ISSN号 | 0567-7351 |
| 中文摘要 | An electrosynthesis in concentrated NaOH electrolyte is first presented for the synthesis of 0.83 mol.L-1 Na2FeO4 solution, and then for the synthesis of solid K3Na(FeO4)(2) with high purity and yield. The synthesis conditions have been explored. Many experiment techniques have been used to characterize the obtained solid sample. The experiment results showed that in the mixed NaOH-KOH solutions, the dissolution-precipitation curve of K3Na(FeO4)(2) conformed to the empirical foumula of [Na+][K+](3) x [FeO42-](2.8) = 1.4 x 10(-4) ([K+] <= 1.01 mol.L-1). The measured solubility of K3Na(FeO4)(2) in concentrated KOH electrolytes was almost the same as that of K2FeO4. Different from K2FeO4 crystals, the synthesized K3Na(FeO4)(2) powders exhibited three characteristic IR absorption peaks (787, 801 similar to 802 and 858 similar to 862 cm(-1)) and a hexagonal unit cell with the space group P3 ml (164). The results of TG/DSC experiments showed that the K3Na(FeO4)(2) powders would not decompose until 197 degrees C in the atmosphere of Ar, but were less stable than K2FeO4. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/33579]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | W. C. He,J. M. Wang,L. Zhou,et al. Study on the synthesis and physicochemistry properties of tripotassium sodium Ferrate(VI)[J]. Acta Chimica Sinica,2007,65(20):2261-2265. |
| APA | W. C. He,J. M. Wang,L. Zhou,Q. Q. Chen,B. C. Shen,&J. Q. Zhang.(2007).Study on the synthesis and physicochemistry properties of tripotassium sodium Ferrate(VI).Acta Chimica Sinica,65(20),2261-2265. |
| MLA | W. C. He,et al."Study on the synthesis and physicochemistry properties of tripotassium sodium Ferrate(VI)".Acta Chimica Sinica 65.20(2007):2261-2265. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。