In situ formation of Ti hydride and its catalytic effect in doped NaAlH4 prepared by milling NaH/Al with metallic Ti powder
文献类型：期刊论文
| 作者 | X. D. Kang ; P. Wang ; H. M. Cheng |
| 刊名 | International Journal of Hydrogen Energy
 |
| 出版日期 | 2007 |
| 卷号 | 32期号:14页码:2943-2948 |
| 关键词 | hydrogen storage NaAlH4 metallic Ti Ti hydride active species sodium aluminum-hydride reversible hydrogen storage x-ray-diffraction titanium alanates state spectroscopy absorption precursors zirconium |
| ISSN号 | 0360-3199 |
| 中文摘要 | X-ray diffraction (XRD) analysis revealed that nanocrystalline Ti hydride(s) was in situ formed during mechanical milling 1:1 NaH/AI mixture with metallic Ti powder. The composition of the formed Ti hydrides varies slightly upon changing the milling atmosphere from inert Ar to reactive H-2. Directly doping sodium alanate with commercial Ti hydride was found to result in similar dehydriding kinetics, hydrogen capacity, and cycling stability to those of the samples doped with metallic Ti. Moreover, according to the XRD results, the Ti hydride(s) remains stable in the de-/hydrogenation cycles. On the basis of these results, a discussion regarding the nature of catalytically active species was given. (c) 2007 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/33614]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | X. D. Kang,P. Wang,H. M. Cheng. In situ formation of Ti hydride and its catalytic effect in doped NaAlH4 prepared by milling NaH/Al with metallic Ti powder[J]. International Journal of Hydrogen Energy,2007,32(14):2943-2948. |
| APA | X. D. Kang,P. Wang,&H. M. Cheng.(2007).In situ formation of Ti hydride and its catalytic effect in doped NaAlH4 prepared by milling NaH/Al with metallic Ti powder.International Journal of Hydrogen Energy,32(14),2943-2948. |
| MLA | X. D. Kang,et al."In situ formation of Ti hydride and its catalytic effect in doped NaAlH4 prepared by milling NaH/Al with metallic Ti powder".International Journal of Hydrogen Energy 32.14(2007):2943-2948. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。