Advantage of TiF(3) over TiCl(3) as a dopant precursor to improve the thermodynamic property of Na(3)AlH(6)
文献类型：期刊论文
| 作者 | X. D. Kang ; P. Wang ; H. M. Cheng |
| 刊名 | Scripta Materialia
 |
| 出版日期 | 2007 |
| 卷号 | 56期号:5页码:361-364 |
| 关键词 | hydrogen storage sodium alanate catalysis thermodynamics sodium aluminum-hydride hydrogen-storage material doped naalh4 x-ray metal-hydrides state diffraction dependence powder nah/al |
| ISSN号 | 1359-6462 |
| 中文摘要 | The effect of the dopant anion on thermodynamic tailoring in TiF(3)- and TiCl(3)-doped Na(3)AlH(6) was investigated by pressure-composition desorption isotherm measurements. It was found that the dissociation pressure of the TiF(3)-doped hydride was substantially higher than that of the TiCl(3)-doped sample. This finding agrees well with the theoretically demonstrated thermodynamic modification arising upon F(-) substitution in the hydride lattice, thus providing direct experimental evidence to support functionality of F(-) anion. (c) 2006 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/33616]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | X. D. Kang,P. Wang,H. M. Cheng. Advantage of TiF(3) over TiCl(3) as a dopant precursor to improve the thermodynamic property of Na(3)AlH(6)[J]. Scripta Materialia,2007,56(5):361-364. |
| APA | X. D. Kang,P. Wang,&H. M. Cheng.(2007).Advantage of TiF(3) over TiCl(3) as a dopant precursor to improve the thermodynamic property of Na(3)AlH(6).Scripta Materialia,56(5),361-364. |
| MLA | X. D. Kang,et al."Advantage of TiF(3) over TiCl(3) as a dopant precursor to improve the thermodynamic property of Na(3)AlH(6)".Scripta Materialia 56.5(2007):361-364. |
入库方式： OAI收割
来源：金属研究所
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