Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (III): Equation of state and fluctuations
文献类型:期刊论文
作者 | H. J. Wang ; F. Gu ; X. Z. Hong ; X. W. Ba |
刊名 | Science in China Series B-Chemistry
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出版日期 | 2007 |
卷号 | 50期号:2页码:183-189 |
关键词 | hydrogen bonding fluid equation of state fluctuation correlation effect liquid methanol temperature water dependence |
ISSN号 | 1006-9291 |
中文摘要 | The equation of the state of the hydrogen bonding fluid system of A(a)D(d) type is studied by the principle of statistical mechanics. The influences of hydrogen bonds on the equation of state of the system are obtained based on the change in volume due to hydrogen bonds. Moreover, the number density fluctuations of both molecules and hydrogen bonds as well as their spatial correlation property are investigated. Furthermore, an equation describing relation between the number density correlation function of "molecules-hydrogen bonds" and that of molecules and hydrogen bonds is derived. As application, taking the van der Waals hydrogen bonding fluid as an example, we considered the effect of hydrogen bonds on its relevant statistical properties. |
原文出处 | |
公开日期 | 2012-04-13 |
源URL | [http://ir.imr.ac.cn/handle/321006/33858] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | H. J. Wang,F. Gu,X. Z. Hong,et al. Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (III): Equation of state and fluctuations[J]. Science in China Series B-Chemistry,2007,50(2):183-189. |
APA | H. J. Wang,F. Gu,X. Z. Hong,&X. W. Ba.(2007).Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (III): Equation of state and fluctuations.Science in China Series B-Chemistry,50(2),183-189. |
MLA | H. J. Wang,et al."Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (III): Equation of state and fluctuations".Science in China Series B-Chemistry 50.2(2007):183-189. |
入库方式: OAI收割
来源:金属研究所
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