Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (II): Properties of hydrogen bonding networks
文献类型:期刊论文
作者 | H. J. Wang ; X. Z. Hong ; F. Gu ; X. W. Ba |
刊名 | Science in China Series B-Chemistry
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出版日期 | 2007 |
卷号 | 50期号:1页码:41230 |
关键词 | hydrogen bonding network gel phase scaling thermoreversible gelation liquid water computer-simulations dynamics polymerization polymers |
ISSN号 | 1006-9291 |
中文摘要 | Making use of the invariant property of the equilibrium size distribution of the hydrogen bonding clusters formed in hydrogen bonding system of A(a)D(d) type, the analytical expressions of the free energy in pregel and postgel regimes are obtained. Then the gel free energy and the scaling behavior of the number of hydrogen bonds in gel phase near the critical point are investigated to give the corresponding scaling exponents and scaling law. Meanwhile, some properties of intermolecular and intramolecular hydrogen bonds in the system, sol and gel phases are discussed. As a result, the explicit relationship between the number of intramolecular hydrogen bonds and hydrogen bonding degree is obtained. |
原文出处 | |
公开日期 | 2012-04-13 |
源URL | [http://ir.imr.ac.cn/handle/321006/33860] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | H. J. Wang,X. Z. Hong,F. Gu,et al. Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (II): Properties of hydrogen bonding networks[J]. Science in China Series B-Chemistry,2007,50(1):41230. |
APA | H. J. Wang,X. Z. Hong,F. Gu,&X. W. Ba.(2007).Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (II): Properties of hydrogen bonding networks.Science in China Series B-Chemistry,50(1),41230. |
MLA | H. J. Wang,et al."Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (II): Properties of hydrogen bonding networks".Science in China Series B-Chemistry 50.1(2007):41230. |
入库方式: OAI收割
来源:金属研究所
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