Electron paramagnetic resonance parameters and local structure for Gd3+ in KY3F10
文献类型：期刊论文
| 作者 | S. Y. Wu ; H. M. Zhang ; G. D. Lu ; Z. H. Zhang |
| 刊名 | Pramana-Journal of Physics
 |
| 出版日期 | 2007 |
| 卷号 | 69期号:3页码:451-457 |
| 关键词 | electron paramagnetic resonance crystal fields and spin hamiltonians Gd3+ KY3F10 energy-transfer processes crystal-field parameters van-vleck paramagnets single-crystals superposition-model optical-properties spectroscopy ions liyf4 state |
| ISSN号 | 0304-4289 |
| 中文摘要 | The electron paramagnetic resonance parameters, zero-field splittings (ZFSs) b(2)(0), b(4)(0), b(4)(4), b(6)(0), b(6)(4) and the g factors for Gd3+ on the tetragonal Y3+ site in KY3F10 are theoretically studied from the superposition model for the ZFSs and the approximation formula for the g factor containing the admixture of the ground S-8(7/2) and the excited L-6(7/2) (L= P, D, F, G) states via the spin-orbit coupling interactions, respectively. By analysing the above ZFSs, the local structure information for the impurity Gd3+ is obtained, i.e., the impurity-ligand bonding angles related to the four-fold (C-4) axis for the impurity Gd3+ center are found to be about 0.6. larger than those for the host Y3+ site in KY3F10. The calculated ZFSs based on the above angular distortion as well as the g factors are in reasonable agreement with the observed values. The present studies on the ZFSs and the local structure would be helpful to understand the optical and magnetic properties of this material with Gd dopants. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/33920]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | S. Y. Wu,H. M. Zhang,G. D. Lu,et al. Electron paramagnetic resonance parameters and local structure for Gd3+ in KY3F10[J]. Pramana-Journal of Physics,2007,69(3):451-457. |
| APA | S. Y. Wu,H. M. Zhang,G. D. Lu,&Z. H. Zhang.(2007).Electron paramagnetic resonance parameters and local structure for Gd3+ in KY3F10.Pramana-Journal of Physics,69(3),451-457. |
| MLA | S. Y. Wu,et al."Electron paramagnetic resonance parameters and local structure for Gd3+ in KY3F10".Pramana-Journal of Physics 69.3(2007):451-457. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。