Investigations on the superhyperfine parameters for Cr3+ in the fluorides
文献类型：期刊论文
| 作者 | J. S. Yao ; S. Y. Wu ; X. Y. Gao ; H. M. Zhang |
| 刊名 | Hyperfine Interactions
 |
| 出版日期 | 2007 |
| 卷号 | 174期号:1-3页码:103-109 |
| 关键词 | hyperfine interactions d3 crystal- and ligand-field theory 7 ions Cr3+ fluorides atomic screening constants crystal-field spectra hyperfine-structure resonance spectra scf functions spin |
| ISSN号 | 0304-3843 |
| 中文摘要 | The superhyperfine parameters A' and B' for Cr3+ ions in K2NaGaF6, K2NaCrF6, KMgF3 and CsCdF3 are theoretically studied from the cluster approach. In the present treatments, the orbital admixture coefficients and the unpaired spin densities in 2s, 2p(sigma) and 2p(pi)2 fluorine orbitals are obtained in a uniform way. The experimental A' and B' are reasonably explained, and the unpaired spin densities for the 2s, 2ps and 2p pi orbitals of the ligand F- are also compared with those in the previous works. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/33982]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | J. S. Yao,S. Y. Wu,X. Y. Gao,et al. Investigations on the superhyperfine parameters for Cr3+ in the fluorides[J]. Hyperfine Interactions,2007,174(1-3):103-109. |
| APA | J. S. Yao,S. Y. Wu,X. Y. Gao,&H. M. Zhang.(2007).Investigations on the superhyperfine parameters for Cr3+ in the fluorides.Hyperfine Interactions,174(1-3),103-109. |
| MLA | J. S. Yao,et al."Investigations on the superhyperfine parameters for Cr3+ in the fluorides".Hyperfine Interactions 174.1-3(2007):103-109. |
入库方式： OAI收割
来源：金属研究所
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