Metallic and carbon nanotube-catalyzed coupling of hydrogenation in magnesium
文献类型：期刊论文
| 作者 | X. D. Yao ; C. Z. Wu ; A. J. Du ; J. Zou ; Z. H. Zhu ; P. Wang ; H. M. Cheng ; S. Smith ; G. Q. Lu |
| 刊名 | Journal of the American Chemical Society
 |
| 出版日期 | 2007 |
| 卷号 | 129期号:50页码:15650-15654 |
| 关键词 | ab-initio mg(0001) surface storage hydride absorption ti nanocomposites decomposition desorption additives |
| ISSN号 | 0002-7863 |
| 中文摘要 | Synergistic effect of metallic couple and carbon nanotubes on Mg results in an ultrafast kinetics of hydrogenation that overcome a critical barrier of practical use of Mg as hydrogen storage materials. The ultrafast kinetics is attributed to the metal-H atomic interaction at the Mg surface and in the bulk (energy for bonding and releasing) and atomic hydrogen diffusion along the grain boundaries (aggregation of carbon nanotubes) and inside the grains. Hence, a hydrogenation mechanism is presented. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/33990]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | X. D. Yao,C. Z. Wu,A. J. Du,et al. Metallic and carbon nanotube-catalyzed coupling of hydrogenation in magnesium[J]. Journal of the American Chemical Society,2007,129(50):15650-15654. |
| APA | X. D. Yao.,C. Z. Wu.,A. J. Du.,J. Zou.,Z. H. Zhu.,...&G. Q. Lu.(2007).Metallic and carbon nanotube-catalyzed coupling of hydrogenation in magnesium.Journal of the American Chemical Society,129(50),15650-15654. |
| MLA | X. D. Yao,et al."Metallic and carbon nanotube-catalyzed coupling of hydrogenation in magnesium".Journal of the American Chemical Society 129.50(2007):15650-15654. |
入库方式： OAI收割
来源：金属研究所
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