中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Phase relations of the Ag-Ga-N system

文献类型:期刊论文

作者Y. Zhang ; J. K. Liang ; J. B. Li ; Q. L. Liu ; Y. G. Xiao ; Q. Zhang ; B. J. Sun ; G. H. Rao
刊名Journal of Alloys and Compounds
出版日期2007
卷号429期号:1-2页码:184-191
关键词X-ray powder diffraction phase relations GaN Ag-Ga system Ag-Ga-N system silver-gallium equilibrium diagram alloys growth zeta cr diffraction refinement region copper
ISSN号0925-8388
中文摘要The phase diagram of the Ag-Ga binary system and the phase relations of the Ag-Ga-N system are studied by DTA and X-ray powder diffraction. The equilibrium phase diagram of the Ag-Ga system is reconstructed. Two intermetallic phases are determined in the Ag-Ga system: the Ag2Ga compound and a novel delta-Ag3Ga2 with the composition about 40 at.% Ga. The novel phase delta-Ag3Ga2 which is the product of the peritectic reaction Ag2Ga + L <-> delta-Ag3Ga2 at 575 K is indexed with an orthorhomic lattice with lattice parameters a = 6.7276(2) angstrom, b = 3.8840(1) angstrom, c = 3.2200(1) angstrom and V = 84.14 angstrom(3). The temperature-dependent lattice parameters of zeta'-Ag2Ga with 28 at.% Ga are measured by temperature-dependent X-ray powder diffraction from 93 to 543 K. The linear temperature dependences of the expansion coefficients along the direction of a- and c-axis and volume coefficients are obtained, alpha(a) = (1.4741 + 0.0028 T) x 10(-5), alpha(c) = (1.1710 + 9.1349 x 10(-4) T) x 10(-5) and alpha(V) = (4.1167 + 0.0065 T ) x 10(-5), respectively. No ternary phase is found in the Ag-Ga-N system and no solubility of Ag in GaN is observed under the present experimental conditions. (c) 2006 Elsevier B.V. All rights reserved.
原文出处://WOS:000244673100031
公开日期2012-04-13
源URL[http://ir.imr.ac.cn/handle/321006/34056]  
专题金属研究所_中国科学院金属研究所
推荐引用方式
GB/T 7714
Y. Zhang,J. K. Liang,J. B. Li,et al. Phase relations of the Ag-Ga-N system[J]. Journal of Alloys and Compounds,2007,429(1-2):184-191.
APA Y. Zhang.,J. K. Liang.,J. B. Li.,Q. L. Liu.,Y. G. Xiao.,...&G. H. Rao.(2007).Phase relations of the Ag-Ga-N system.Journal of Alloys and Compounds,429(1-2),184-191.
MLA Y. Zhang,et al."Phase relations of the Ag-Ga-N system".Journal of Alloys and Compounds 429.1-2(2007):184-191.

入库方式: OAI收割

来源:金属研究所

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