Ni-Sm0.2Ce0.8O1.9 anode-supported YSZ electrolyte film and its application in solid oxide fuel
文献类型:期刊论文
作者 | Y. H. Zhang ; X. Q. Huang ; Z. Lu ; Z. G. Liu ; X. D. Ge ; H. H. Xu ; X. S. Xin ; X. Q. Sha ; W. H. Su |
刊名 | Journal of Alloys and Compounds
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出版日期 | 2007 |
卷号 | 428期号:1-2页码:302-306 |
关键词 | ceramics fuel cells thin films electrochemical impedance spectroscopy scanning electron microscopy direct oxidation doped ceria cells fabrication methane sofcs |
ISSN号 | 0925-8388 |
中文摘要 | Ni-Sm0.2Ce0.8O1.9 anode-supported YSZ electrolyte films were fabricated and a fuel cell based on this film was tested in this paper. The anode/YSZ film interface was investigated by means of SEM-EDX. The SEM results showed that the YSZ film was almost fully dense and crack-free. The analyses of EDX revealed that Ce and Sm cations preferential migrated from the NiO-SDC anode into the YSZ film for less than 3 mu m while no significant diffusion occurred for Y and Zr. A cell of Ni-SDC/YSZ(14 mu m)/LSM-YSZ was tested from 700 to 850 degrees C using humidified hydrogen as fuel and ambient air as oxidant. The cell provided maximum power densities of 304, 625, 980 and 1270 mW/cm(2) at 700, 750, 800 and 850 degrees C, respectively. Polarization analysis based on the impedance spectra showed that the anode polarization only accounted for 8% of the total electrode polarization while this ratio for cathode was 92%. A negligible anode polarization suggested that the diffusion of Cc and Sm and its negative effect on the performance of the cell were suppressed to an acceptable level in this study. (c) 2006 Elsevier B.V. All rights reserved. |
原文出处 | |
公开日期 | 2012-04-13 |
源URL | [http://ir.imr.ac.cn/handle/321006/34057] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | Y. H. Zhang,X. Q. Huang,Z. Lu,et al. Ni-Sm0.2Ce0.8O1.9 anode-supported YSZ electrolyte film and its application in solid oxide fuel[J]. Journal of Alloys and Compounds,2007,428(1-2):302-306. |
APA | Y. H. Zhang.,X. Q. Huang.,Z. Lu.,Z. G. Liu.,X. D. Ge.,...&W. H. Su.(2007).Ni-Sm0.2Ce0.8O1.9 anode-supported YSZ electrolyte film and its application in solid oxide fuel.Journal of Alloys and Compounds,428(1-2),302-306. |
MLA | Y. H. Zhang,et al."Ni-Sm0.2Ce0.8O1.9 anode-supported YSZ electrolyte film and its application in solid oxide fuel".Journal of Alloys and Compounds 428.1-2(2007):302-306. |
入库方式: OAI收割
来源:金属研究所
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