EPR zero-field splitting parameters and structural distortion study of Mn2+-doped (CH3)(4)NCdCl3 crystal in high-temperature phases
文献类型：期刊论文
| 作者 | D. Dong ; X. Y. Kuang ; H. J. Guo ; W. Hui ; Z. Kang-Wei |
| 刊名 | Chemical Physics Letters
 |
| 出版日期 | 2006 |
| 卷号 | 426期号:1-3页码:77-80 |
| 关键词 | tetramethylammonium cadmium chloride magnetic-resonance domain-structure tmcc ions transitions fe-3+ mn2 |
| ISSN号 | 0009-2614 |
| 中文摘要 | The EPR zero-field splitting parameters and structural distortion of Mn2+-doped (CH3)(4)NCdCl3 crystal in high-temperature phases have been studied by diagonalizing the complete energy matrices. The zero-field splitting parameters D and (a - F) are demonstrated to be negative and positive, respectively, and obtain a reasonable explanation together. Simultaneously, the distortion magnitude of local lattice structure around the Mn2+ ion in this. crystal is determined, namely, Delta R = -0.13 angstrom and Delta theta = 2.975 degrees for T = 124 K; Delta R = -0.12 angstrom and Delta theta = 2.610 degrees for T = 297 K; Delta R = -0.26 angstrom and Delta O = 2.870 degrees for T = 573 K. From the structural distortion, we deduce that a new structural phase transition should occur to the (CH3)(4)NCdCl3 crystal at temperatures ranging from 297 to 573 K. This is also in agreement with recent differential scanning calorimetric measurements. (c) 2006 Elsevier B.V. All rights reserved. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/34172]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | D. Dong,X. Y. Kuang,H. J. Guo,et al. EPR zero-field splitting parameters and structural distortion study of Mn2+-doped (CH3)(4)NCdCl3 crystal in high-temperature phases[J]. Chemical Physics Letters,2006,426(1-3):77-80. |
| APA | D. Dong,X. Y. Kuang,H. J. Guo,W. Hui,&Z. Kang-Wei.(2006).EPR zero-field splitting parameters and structural distortion study of Mn2+-doped (CH3)(4)NCdCl3 crystal in high-temperature phases.Chemical Physics Letters,426(1-3),77-80. |
| MLA | D. Dong,et al."EPR zero-field splitting parameters and structural distortion study of Mn2+-doped (CH3)(4)NCdCl3 crystal in high-temperature phases".Chemical Physics Letters 426.1-3(2006):77-80. |
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来源：金属研究所
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