The internal oxidation of ternary alloys. VII: The transition from the internal to the external oxidation of the two most-reactive components under intermediate oxidant pressures
文献类型:期刊论文
作者 | F. Gesmundo ; Y. Niu |
刊名 | Oxidation of Metals
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出版日期 | 2006 |
卷号 | 66期号:1-2页码:69-89 |
关键词 | ternary alloys single oxidant internal oxidation low oxidant pressures degrees c diffusion kinetics scale aluminum nickel |
ISSN号 | 0030-770X |
中文摘要 | The conditions for the transition between the coupled internal oxidation of two most-reactive components and the formation of external scales in the scaling of ternary alloys under oxidant pressures below the stability of the oxide of the most-noble component, denoted as a situation of intermediate oxidant pressures, are examined under a number of simplifying conditions which allow to develop an approximate analytical treatment. If the precipitation of the two oxides occurs at the same front of internal oxidation, the kinetics of internal oxidation as well as the critical B and C contents needed for the transition have a single solution under fixed conditions of all the parameters involved. Oil the contrary, in the presence of two different fronts, when the most-stable oxide forms at the innermost front, a whole range of possible solutions is predicted. In both cases, the critical-C content needed to avoid the simultaneous internal oxidation of B plus C is progressively reduced by the addition of B. This behavior provides the basis for a possible interpretation of the "third-element effect". However, the existence and the magnitude of this effect are complicated by the occurrence of other modes of oxidation for these systems. Thus, a general treatment of the third-element effect under intermediate oxidant pressures requires an exhaustive analysis of all the oxidation modes permitted for ternary alloys under these conditions. |
原文出处 | |
公开日期 | 2012-04-13 |
源URL | [http://ir.imr.ac.cn/handle/321006/34219] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | F. Gesmundo,Y. Niu. The internal oxidation of ternary alloys. VII: The transition from the internal to the external oxidation of the two most-reactive components under intermediate oxidant pressures[J]. Oxidation of Metals,2006,66(1-2):69-89. |
APA | F. Gesmundo,&Y. Niu.(2006).The internal oxidation of ternary alloys. VII: The transition from the internal to the external oxidation of the two most-reactive components under intermediate oxidant pressures.Oxidation of Metals,66(1-2),69-89. |
MLA | F. Gesmundo,et al."The internal oxidation of ternary alloys. VII: The transition from the internal to the external oxidation of the two most-reactive components under intermediate oxidant pressures".Oxidation of Metals 66.1-2(2006):69-89. |
入库方式: OAI收割
来源:金属研究所
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