A study of the inhibiton of copper corrosion by triethyl phosphate and triphenyl phosphate self-assembled monolayers
文献类型：期刊论文
| 作者 | W. J. Guo ; S. H. Chen ; H. Y. Ma |
| 刊名 | Journal of the Serbian Chemical Society
 |
| 出版日期 | 2006 |
| 卷号 | 71期号:2页码:167-175 |
| 关键词 | copper phosphates self-assembled monolayers (SAMs) electrochemical impedance spectroscopy (EIS) ab initio calculation scanning-tunneling-microscopy hydrochloric-acid solution schiff-bases n-alkanethiols chain-length protection surfaces films electrodissolution impedance |
| ISSN号 | 0352-5139 |
| 中文摘要 | Two kinds of phosphates, triethyl phosphate (TEP) and triphenyl phosphate (TPP), were used to form self-assembled monolayers for the inhibition of the corrosion of copper in 0.2 mol dm(-3) NaCl solution. Electrochemical impedance spectroscopy (EIS) was applied to investigate the inhibition effects. The results showed that their inhibition ability first increased with increasing immersion time in ethanolic solutions of the corresponding compounds. However, when the immersion time was increased over some critical point, the inhibition effect decreased. For the same immersion time, the inhibition effect of the TPP monolayer was more pronounced than that of the TEP monolayer. Thus, ab initio calculations were used to interpret the relationship between the inhibition effects and the structures of the compounds. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/34229]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | W. J. Guo,S. H. Chen,H. Y. Ma. A study of the inhibiton of copper corrosion by triethyl phosphate and triphenyl phosphate self-assembled monolayers[J]. Journal of the Serbian Chemical Society,2006,71(2):167-175. |
| APA | W. J. Guo,S. H. Chen,&H. Y. Ma.(2006).A study of the inhibiton of copper corrosion by triethyl phosphate and triphenyl phosphate self-assembled monolayers.Journal of the Serbian Chemical Society,71(2),167-175. |
| MLA | W. J. Guo,et al."A study of the inhibiton of copper corrosion by triethyl phosphate and triphenyl phosphate self-assembled monolayers".Journal of the Serbian Chemical Society 71.2(2006):167-175. |
入库方式： OAI收割
来源：金属研究所
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