Catalytic effect of Al(3)Ti on the reversible dehydrogenation of NaAlH(4)
文献类型：期刊论文
| 作者 | X. D. Kang ; P. Wang ; X. P. Song ; X. D. Yao ; G. Q. Lu ; H. M. Cheng |
| 刊名 | Journal of Alloys and Compounds
 |
| 出版日期 | 2006 |
| 卷号 | 424期号:1-2页码:365-369 |
| 关键词 | hydrogen storage materials NaAlH(4) catalysis kinetics X-ray diffraction sodium aluminum-hydride ti-doped naalh4 hydrogen storage properties x-ray-absorption metal-hydrides titanium state lialh4 spectroscopy diffraction |
| ISSN号 | 0925-8388 |
| 中文摘要 | Al(3)Ti was directly utilized as catalyst precursor to examine its catalytic activity in the reversible dehydrogenation of NaAlH(4). It was observed that Al(3)Ti possessed considerable catalytic effect on the de-/hydriding reactions of NaAlH(4). The catalytic enhancement by Al(3)Ti doping significantly increased with increasing ball-milling time. Moreover, it was noted that dehydriding kinetics and cycling performance of the Al(3)Ti-doped NaAlH(4) were highly dependent on the starting material, 1:1 NaH/Al mixture or NaAlH(4). The combined property and phase examinations suggest that Al(3)Ti may act as active species to catalyze the reversible de-/hydrogenation of NaAlH(4). (c) 2006 Published by Elsevier B.V. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/34283]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | X. D. Kang,P. Wang,X. P. Song,et al. Catalytic effect of Al(3)Ti on the reversible dehydrogenation of NaAlH(4)[J]. Journal of Alloys and Compounds,2006,424(1-2):365-369. |
| APA | X. D. Kang,P. Wang,X. P. Song,X. D. Yao,G. Q. Lu,&H. M. Cheng.(2006).Catalytic effect of Al(3)Ti on the reversible dehydrogenation of NaAlH(4).Journal of Alloys and Compounds,424(1-2),365-369. |
| MLA | X. D. Kang,et al."Catalytic effect of Al(3)Ti on the reversible dehydrogenation of NaAlH(4)".Journal of Alloys and Compounds 424.1-2(2006):365-369. |
入库方式： OAI收割
来源：金属研究所
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