The EPR zero-field splitting D and its pressure and temperature dependence for trigonal Mn2+ centers in Zn(H2O)(6) (BF4)(2): Mn2+ crystal
文献类型:期刊论文
作者 | H. G. Liu ; X. X. Wu ; W. C. Zheng ; L. He |
刊名 | Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences
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出版日期 | 2006 |
卷号 | 61期号:5-6页码:289-292 |
关键词 | electron paramagnetic resonance crystal- and ligand-field theory defect structure and properties Mn2+ [Zn(H2O)(6)](BF4)(2) phase-transitions ion spectrum co2+ impurities symmetry 6h(2)o mn-2 ni |
ISSN号 | 0932-0784 |
中文摘要 | The EPR zero-field splitting D (= b(2)(0)) and its pressure and temperature dependence for trigonal Mn2+ centers in low and room temperature phases in [Zn(H2O)(6)](BF4)(2) : Mn2+ crystal are studied by a high-order perturbation formula based on the dominant spin-orbit coupling mechanism. From the studies, the local trigonal distortion angles, the local angular compressibilities and the local angular thermal expansion coefficients for Mn2+ centers in both phases of the [Zn(H2O)(6)](BF4)(2) crystal are estimated. The results are discussed. |
原文出处 | |
公开日期 | 2012-04-13 |
源URL | [http://ir.imr.ac.cn/handle/321006/34357] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | H. G. Liu,X. X. Wu,W. C. Zheng,et al. The EPR zero-field splitting D and its pressure and temperature dependence for trigonal Mn2+ centers in Zn(H2O)(6) (BF4)(2): Mn2+ crystal[J]. Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,2006,61(5-6):289-292. |
APA | H. G. Liu,X. X. Wu,W. C. Zheng,&L. He.(2006).The EPR zero-field splitting D and its pressure and temperature dependence for trigonal Mn2+ centers in Zn(H2O)(6) (BF4)(2): Mn2+ crystal.Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,61(5-6),289-292. |
MLA | H. G. Liu,et al."The EPR zero-field splitting D and its pressure and temperature dependence for trigonal Mn2+ centers in Zn(H2O)(6) (BF4)(2): Mn2+ crystal".Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences 61.5-6(2006):289-292. |
入库方式: OAI收割
来源:金属研究所
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