中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Electrochemical impedance spectroscopy (EIS) studies of the corrosion of pure Fe and Cr at 600 circle C under solid NaCl deposit in water vapor

文献类型:期刊论文

作者L. Liu ; Y. Li ; C. L. Zeng ; F. H. Wang
刊名Electrochimica Acta
出版日期2006
卷号51期号:22页码:4736-4743
关键词solid NaCl water vapor EIS high temperature corrosion oxidation temperature aqueous-electrolytes mixed-conduction model oxide-films ionic-conductivity stainless-steels preoxidized ni hot-corrosion na2so4 film behavior alloys
ISSN号0013-4686
中文摘要The corrosion behavior of pure Fe and pure Cr at 600 degrees C under a deposit of solid NaCl, with and without the presence of water vapor, was studied by using electrochemical impedance spectroscopy (EIS) and mass gain measurements. The mass gain of both metals sharply increased when water vapor was introduced into the system. In EIS measurement, only one capacitive loop obtained on the pure Fe and Cr coated with solid NaCl and gave the information of oxide layer on them. For the oxide in air, there is a good relationship between the R-ox and the reaction rate for both pure Fe and Cr with different oxide time. The lower the R-ox is, the higher the reaction rate is. Although no good relationship can be set up between the R-ox and the reaction rate when water vapor presented, its trend with oxide time for both metals is generally in accordance with that of the corrosion rate measured by the mass gain curves. The electrochemical technique is an effective method for studying corrosion performance at high temperature. (c) 2006 Published by Elsevier Ltd.
原文出处://WOS:000238752600021
公开日期2012-04-13
源URL[http://ir.imr.ac.cn/handle/321006/34367]  
专题金属研究所_中国科学院金属研究所
推荐引用方式
GB/T 7714
L. Liu,Y. Li,C. L. Zeng,et al. Electrochemical impedance spectroscopy (EIS) studies of the corrosion of pure Fe and Cr at 600 circle C under solid NaCl deposit in water vapor[J]. Electrochimica Acta,2006,51(22):4736-4743.
APA L. Liu,Y. Li,C. L. Zeng,&F. H. Wang.(2006).Electrochemical impedance spectroscopy (EIS) studies of the corrosion of pure Fe and Cr at 600 circle C under solid NaCl deposit in water vapor.Electrochimica Acta,51(22),4736-4743.
MLA L. Liu,et al."Electrochemical impedance spectroscopy (EIS) studies of the corrosion of pure Fe and Cr at 600 circle C under solid NaCl deposit in water vapor".Electrochimica Acta 51.22(2006):4736-4743.

入库方式: OAI收割

来源:金属研究所

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