Microstructural evolution of bulk polycrystalline La0.7-xLuxSr0.3MnO3 (x=0.2, 0.45, 0.6) compounds
文献类型:期刊论文
作者 | B. Z. Sun ; L. L. He ; F. Luo ; C. H. Yan |
刊名 | Materials Chemistry and Physics
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出版日期 | 2006 |
卷号 | 98期号:2-3页码:415-418 |
关键词 | crystal structure microstructure substitution lattice parameters atomic ratio giant magnetoresistance transport-properties granular perovskites double-exchange phase-diagram doped lamno3 la1-xsrxmno3 films transition |
ISSN号 | 0254-0584 |
中文摘要 | Crystal structure and microstructure of La0.7-xLuxSr0.3MnO3 (x = 0.2 0.45, 0.6) prepared by usual ceramic techniques and grinding procedure are studied using X-ray diffraction (XRD) and transmission electron microscopy (TEM). With substitution of Lu3+ for La3+ and Sr2+, LSMO rhombohedral phase has been gradually converted to the stable hexagonal phase LuMnO3. Surprisingly, XRD and the energy-dispersive X-ray spectroscopy (EDS) analyses have demonstrated that both lattice parameters (a- and c-lengths) and the La3+/Sr2+ atomic ratio of the rhombohedral phase are decreasing with increasing x. The abnormal phenomenon is related to the fact that the Mn3+/Mn4+ atomic ratio in the reactant is changed accompanying with combination of Lu3+ and Mn2O3. (c) 2005 Elsevier B.V. All rights reserved. |
原文出处 | |
公开日期 | 2012-04-14 |
源URL | [http://ir.imr.ac.cn/handle/321006/34466] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | B. Z. Sun,L. L. He,F. Luo,et al. Microstructural evolution of bulk polycrystalline La0.7-xLuxSr0.3MnO3 (x=0.2, 0.45, 0.6) compounds[J]. Materials Chemistry and Physics,2006,98(2-3):415-418. |
APA | B. Z. Sun,L. L. He,F. Luo,&C. H. Yan.(2006).Microstructural evolution of bulk polycrystalline La0.7-xLuxSr0.3MnO3 (x=0.2, 0.45, 0.6) compounds.Materials Chemistry and Physics,98(2-3),415-418. |
MLA | B. Z. Sun,et al."Microstructural evolution of bulk polycrystalline La0.7-xLuxSr0.3MnO3 (x=0.2, 0.45, 0.6) compounds".Materials Chemistry and Physics 98.2-3(2006):415-418. |
入库方式: OAI收割
来源:金属研究所
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