Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (I): The geometrical phase transition
文献类型：期刊论文
| 作者 | H. J. Wang ; X. Z. Hong ; F. Gu ; X. W. Ba |
| 刊名 | Science in China Series B-Chemistry
 |
| 出版日期 | 2006 |
| 卷号 | 49期号:6页码:499-506 |
| 关键词 | hydrogen bonding fluid equilibrium free energy geometrical phase transition equation-of-state thermoreversible gelation liquid water computer-simulations dynamics networks polymers models |
| ISSN号 | 1006-9291 |
| 中文摘要 | The influence of hydrogen bonds on the physical and chemical properties of hydrogen bonding fluid system of A(a)D(d) type is investigated from two viewpoints by the principle of statistical mechanics. In detail, we proposed two new ways that can be used to obtain the equilibrium size distribution of the hydrogen bonding clusters, and derived the analytical expression of a relationship between the hydrogen bonding free energy and hydrogen bonding degree. For the nonlinear hydrogen bonding systems, it is shown that the sol-gel phase transition can take place under proper conditions, which is further proven to be a kind of geometrical phase transition rather than a thermodynamic one. Moreover, several problems associated with the geometrical phase transition and liquid-solid phase transition in nonlinear hydrogen bonding systems are discussed. |
| 原文出处 | |
| 公开日期 | 2012-04-14 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/34503]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | H. J. Wang,X. Z. Hong,F. Gu,et al. Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (I): The geometrical phase transition[J]. Science in China Series B-Chemistry,2006,49(6):499-506. |
| APA | H. J. Wang,X. Z. Hong,F. Gu,&X. W. Ba.(2006).Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (I): The geometrical phase transition.Science in China Series B-Chemistry,49(6),499-506. |
| MLA | H. J. Wang,et al."Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (I): The geometrical phase transition".Science in China Series B-Chemistry 49.6(2006):499-506. |
入库方式： OAI收割
来源：金属研究所
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