Oxidation behavior of bulk Ti3SiC2 at intermediate temperatures in dry air
文献类型:期刊论文
作者 | H. B. Zhang ; Y. C. Zhou ; Y. W. Bao ; J. Y. Wang |
刊名 | Journal of Materials Research
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出版日期 | 2006 |
卷号 | 21期号:2页码:402-408 |
关键词 | crack-healing behavior silicon-carbide molybdenum disilicide thermal-oxidation pest silicides ceramics growth transformation strength |
ISSN号 | 0884-2914 |
中文摘要 | The isothermal oxidation behavior of bulk Ti3SiC2 at intermediate temperatures from 500 to 900 degrees C in flowing dry air was investigated. An anomalous oxidation with higher kinetics at lower temperatures was observed. This phenomenon resulted from the formation of microcracks in the oxide scales at low temperatures. The generation of these microcracks was caused by a phase change in the oxide products, i.e., the trans formation of anatase TiO2 to rutile TiO2. This phase trans formation resulted in tensile stress, which provided the driving force for the formation of the microcracks during oxidation. Despite the existence of microcracks, the intermediate-temperature oxidation of Ti3SiC2 generally obeyed the parabolic rate law and did not exhibit catastrophic destruction due to the fact that cracks occurring in the oxide layers were partially filled with amorphous SiO2. Therefore, further high oxidation kinetics was prevented. |
原文出处 | |
公开日期 | 2012-04-14 |
源URL | [http://ir.imr.ac.cn/handle/321006/34691] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | H. B. Zhang,Y. C. Zhou,Y. W. Bao,et al. Oxidation behavior of bulk Ti3SiC2 at intermediate temperatures in dry air[J]. Journal of Materials Research,2006,21(2):402-408. |
APA | H. B. Zhang,Y. C. Zhou,Y. W. Bao,&J. Y. Wang.(2006).Oxidation behavior of bulk Ti3SiC2 at intermediate temperatures in dry air.Journal of Materials Research,21(2),402-408. |
MLA | H. B. Zhang,et al."Oxidation behavior of bulk Ti3SiC2 at intermediate temperatures in dry air".Journal of Materials Research 21.2(2006):402-408. |
入库方式: OAI收割
来源:金属研究所
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