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Zero-field splitting and g-factor studies for 3d(5) ions in tetragonal and trigonal symmetry

文献类型:期刊论文

作者Y. Lei ; X. T. Zu ; M. G. Zhao
刊名Physica B-Condensed Matter
出版日期2005
卷号364期号:1-4页码:122-129
关键词crystal-field theory Zeeman interaction spin-Hamiltonian zero field splitting spin-hamiltonian parameters d-orbital theory fluorides crystals resonance pressure spectrum cluster model fe3+
ISSN号0921-4526
中文摘要In this paper, the rigorous analytical expressions for the zero field splittings D, a, F and g-factors of a 3d(5) ion in tetragonal and trigonal crystal fields are derived. In the derivations, the energy levels equivalence between microscopic Zeeman interaction and phenomenological spin-Hamiltonian was used. The deduced expressions do not depend on any interaction model and are universal expressions. As some examples. we studied the specific examples of MnCO3, Rb2CdF4: Mn2+ and KZnF3: Mn2+. Good agreement between calculation and experiments shows that the formulas are reasonable. (c) 2005 Elsevier B.V. All rights reserved.
原文出处://WOS:000230253100015
公开日期2012-04-14
源URL[http://ir.imr.ac.cn/handle/321006/34893]  
专题金属研究所_中国科学院金属研究所
推荐引用方式
GB/T 7714
Y. Lei,X. T. Zu,M. G. Zhao. Zero-field splitting and g-factor studies for 3d(5) ions in tetragonal and trigonal symmetry[J]. Physica B-Condensed Matter,2005,364(1-4):122-129.
APA Y. Lei,X. T. Zu,&M. G. Zhao.(2005).Zero-field splitting and g-factor studies for 3d(5) ions in tetragonal and trigonal symmetry.Physica B-Condensed Matter,364(1-4),122-129.
MLA Y. Lei,et al."Zero-field splitting and g-factor studies for 3d(5) ions in tetragonal and trigonal symmetry".Physica B-Condensed Matter 364.1-4(2005):122-129.

入库方式: OAI收割

来源:金属研究所

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