Optical properties of (Y1-xTmx)(3)GaO6 and subsolidus phase relation of Y2O3-Ga2O3-Tm2O3
文献类型:期刊论文
作者 | F. S. Liu ; B. J. Sun ; J. K. Liang ; Q. L. Liu ; J. Lub ; Y. Zhang ; L. X. Wang ; J. N. Yao ; G. H. Rao |
刊名 | Journal of Solid State Chemistry
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出版日期 | 2005 |
卷号 | 178期号:4页码:1064-1070 |
关键词 | Tm3+ -doped Y3GaO6 Y2O3-Ga2O3-Tm2O3 system (Y1-xTmx)(3)Ga5O12 solid solution luminescence crystal-structure luminescence phosphor cations ions tb3 |
ISSN号 | 0022-4596 |
中文摘要 | A serial of samples in Y2O3-Ga2O3-Tm2O3 pseudo-ternary system are prepared by solid-state chemical reaction method. The range of solid solution in (Y1-xTmx)(3)GaO6 is 0 < x < 0.384. Powder X-ray diffraction shows that the compounds crystallize in Gd3GaO6 (Cmc2(1))-type structure. The solid solubilities of Y3+xGa5-xO12 (x = 0-0.77) and Tm3+xGa5-xO12 (x = 0-0.62) are 37.5-47.11 at% Y2O3, and 37.5-45.26 at% Tm2O3, respectively. PL spectra of Tm-doped Y3GaO6 show that there is a sharp blue emission at similar to 456 nm from the D-1(2) -> F-3(4) transition at room temperatures with two lifetimes (similar to 5 and similar to 15 mu s) and a narrow saturation range of PL intensity for the Tm3+ content from x = 0.005 to 0.03. The sharp emission and long lifetime of (Y1-xTmx)(3)GaO6 indicate that Y3GaO6 is a potential phosphor and laser crystal host material. (c) 2005 Elsevier Inc. All rights reserved. |
原文出处 | |
公开日期 | 2012-04-14 |
源URL | [http://ir.imr.ac.cn/handle/321006/34933] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | F. S. Liu,B. J. Sun,J. K. Liang,et al. Optical properties of (Y1-xTmx)(3)GaO6 and subsolidus phase relation of Y2O3-Ga2O3-Tm2O3[J]. Journal of Solid State Chemistry,2005,178(4):1064-1070. |
APA | F. S. Liu.,B. J. Sun.,J. K. Liang.,Q. L. Liu.,J. Lub.,...&G. H. Rao.(2005).Optical properties of (Y1-xTmx)(3)GaO6 and subsolidus phase relation of Y2O3-Ga2O3-Tm2O3.Journal of Solid State Chemistry,178(4),1064-1070. |
MLA | F. S. Liu,et al."Optical properties of (Y1-xTmx)(3)GaO6 and subsolidus phase relation of Y2O3-Ga2O3-Tm2O3".Journal of Solid State Chemistry 178.4(2005):1064-1070. |
入库方式: OAI收割
来源:金属研究所
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