EIS study of corrosion behaviour of organic coating/Dacromet composite systems
文献类型:期刊论文
作者 | J. G. Liu ; G. P. Gong ; C. W. Yan |
刊名 | Electrochimica Acta
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出版日期 | 2005 |
卷号 | 50期号:16-17页码:3320-3332 |
关键词 | dacromet EIS corrosion behaviour organic coating composite synergetic effect electrochemical impedance spectroscopy protective-coatings mild-steel paints deterioration degradation performance pigments |
ISSN号 | 0013-4686 |
中文摘要 | Three organic coating/Dacromet composite systems, namely two solvent-borne coatings, polyurethane, alkyd primers and a water-borne coating, styrene-acrylate emulsion, were prepared on Dacrometed carbon steel. Electrochemical impedance spectroscopy (EIS) was employed to study their corrosion behaviour in 3.5% NaCl medium. Characteristic EIS plots with two undistinguishable loops were observed for the styrene-acrylate emulsion/Dacromet system and of which the second one was greatly flatter with immersion time. The stable evolution of R-p, C-p, C-d, and a higher value of R-c illustrated an original fact that the water-borne styrene-acrylate emulsion/Dacromet system exhibited the best protective performance among the three systems. According to the investigation of thin organic film/Dacromet composite systems, a synergetic effect of multiple interface factors including the passivation, the seal and barrier function of insoluble corrosion product of Dacromet, especially the interpenetration of organic micropolymer particle with corrosion product in styrene-acrylate emulsion/Dacromet system was proposed to explain the corrosion behaviour of the composite systems. © 2004 Elsevier Ltd. All rights reserved. |
原文出处 | |
公开日期 | 2012-04-14 |
源URL | [http://ir.imr.ac.cn/handle/321006/34936] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | J. G. Liu,G. P. Gong,C. W. Yan. EIS study of corrosion behaviour of organic coating/Dacromet composite systems[J]. Electrochimica Acta,2005,50(16-17):3320-3332. |
APA | J. G. Liu,G. P. Gong,&C. W. Yan.(2005).EIS study of corrosion behaviour of organic coating/Dacromet composite systems.Electrochimica Acta,50(16-17),3320-3332. |
MLA | J. G. Liu,et al."EIS study of corrosion behaviour of organic coating/Dacromet composite systems".Electrochimica Acta 50.16-17(2005):3320-3332. |
入库方式: OAI收割
来源:金属研究所
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