Studies of EPR parameters and local structure for Cr3+ in NaInS2 crystal
文献类型：期刊论文
| 作者 | Y. Mei ; W. C. Zheng ; X. X. Wu ; Q. Zhou |
| 刊名 | Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences
 |
| 出版日期 | 2005 |
| 卷号 | 60期号:1-2页码:91-94 |
| 关键词 | electron paramagnetic resonance defect structure crystal- and ligand-field theory Cr3+ NaInS2 superposition model analysis electron-paramagnetic-resonance atomic screening constants temperature-dependence single-crystals scf functions field ions fluoroperovskite displacement |
| ISSN号 | 0932-0784 |
| 中文摘要 | The EPR parameters (zero-field splitting D and g factors g(parallel to), g(perpendicular to)) of Cr3+ in a NaInS2 crystal are calculated from high-order perturbation formulas based on the two spin-orbit coupling parameter model for the EPR parameters of 3d(3) ions in trigonal octahedral sites. In the calculations, both the contribution to EPR parameters from the spin-orbit coupling parameter of the central 3d(3) ion and that of ligands are considered. From the calculations it is found that, to explain reasonably the EPR parameters, the local structure (in particular the local trigonal distortion angle theta) in the vicinity of the Cr3+ impurity is different from the corresponding structure in the host crystal. The change of the local angle theta with temperature is also obtained from the temperature dependence of zero-field splitting. The results are discussed. |
| 原文出处 | |
| 公开日期 | 2012-04-14 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/34982]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | Y. Mei,W. C. Zheng,X. X. Wu,et al. Studies of EPR parameters and local structure for Cr3+ in NaInS2 crystal[J]. Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,2005,60(1-2):91-94. |
| APA | Y. Mei,W. C. Zheng,X. X. Wu,&Q. Zhou.(2005).Studies of EPR parameters and local structure for Cr3+ in NaInS2 crystal.Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,60(1-2),91-94. |
| MLA | Y. Mei,et al."Studies of EPR parameters and local structure for Cr3+ in NaInS2 crystal".Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences 60.1-2(2005):91-94. |
入库方式： OAI收割
来源：金属研究所
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