Physical properties and electrochemical performance of LiMn2O4 cathode materials prepared by a precipitation method
文献类型:期刊论文
作者 | G. G. Wang ; J. M. Wang ; W. Q. Mao ; H. B. Shao ; J. Q. Zhang ; C. N. Cao |
刊名 | Journal of Solid State Electrochemistry
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出版日期 | 2005 |
卷号 | 9期号:7页码:524-530 |
关键词 | LiMn2O4 precipitation method cyclic voltammetry electrochemical impedance spectroscopy lithium manganese oxide spinel phase sol-gel pechini process ion batteries drying method electrodes intercalation graphite diffusion |
ISSN号 | 1432-8488 |
中文摘要 | LiMn2O4 powder for lithium-ion batteries was prepared by a precipitation method, and the effects of calcination temperature on the physical properties and electrochemical performance of the samples were investigated by various methods. The results of X-ray diffraction (XRD) showed that the lattice parameter (a) and the unit cell volume (v) decrease with the increasing calcination temperature, and the LiMn2O4 sample calcined at 750 degrees C has smaller particle size and higher crystallinity than other samples. The results of the electrochemical experiments showed that the sample calcined at 750 degrees C has larger peak currents, higher initial capacity, and better cycling capability, because of its lower charge-transfer resistance and larger diffusion coefficient of Li+ ions than those of other samples. |
原文出处 | |
公开日期 | 2012-04-14 |
源URL | [http://ir.imr.ac.cn/handle/321006/35067] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | G. G. Wang,J. M. Wang,W. Q. Mao,et al. Physical properties and electrochemical performance of LiMn2O4 cathode materials prepared by a precipitation method[J]. Journal of Solid State Electrochemistry,2005,9(7):524-530. |
APA | G. G. Wang,J. M. Wang,W. Q. Mao,H. B. Shao,J. Q. Zhang,&C. N. Cao.(2005).Physical properties and electrochemical performance of LiMn2O4 cathode materials prepared by a precipitation method.Journal of Solid State Electrochemistry,9(7),524-530. |
MLA | G. G. Wang,et al."Physical properties and electrochemical performance of LiMn2O4 cathode materials prepared by a precipitation method".Journal of Solid State Electrochemistry 9.7(2005):524-530. |
入库方式: OAI收割
来源:金属研究所
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